KMS Qingdao Institute of Biomass Energy and Bioprocess Technology ,CAS
Chemically modified magnetic chitosan microspheres for Cr(VI) removal from acidic aqueous solution | |
Sun, Xitong1; Li, Qian2; Yang, Liangrong3; Liu, Huizhou1,3 | |
2016-06-01 | |
发表期刊 | PARTICUOLOGY |
卷号 | 26页码:79-86 |
摘要 | A bioadsorbent composed of magnetic silica nanoparticles encapsulated by chitosan microspheres was prepared by the emulsion cross-linking method, and it was then modified with quaternary ammonium groups by reaction with ethylenediamine and glycidyl trimethylammonium chloride. Characterization of the bioadsorbent indicated that it was highly acid resistant and magnetically responsive. The bioadsorbent was then used to remove Cr(VI) from acidic aqueous solution. The results of batch experiments indicated that the optimal pH value was 2.5, and the adsorbent exhibited low pH dependence. The maximum adsorption capacity was 233.1 mg/g at pH 2.5 and 25 degrees C, and the equilibrium time was determined to be 40-120 min depending on the initial Cr(VI) concentration. The adsorbent could be effectively regenerated using a mixture of 0.3 mol/L NaOH and 0.3 mol/L NaCl with a desorption efficiency of 95.6%, indicating high reusability. In conclusion, the bioadsorbent shows potential for Cr(Vl) removal from acidic wastewater. (C) 2016 Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
文章类型 | Article |
关键词 | Chitosan Quaternary Ammonium Magnetic Adsorption Cr(Vl) |
WOS标题词 | Science & Technology ; Technology |
DOI | 10.1016/j.partic.2015.11.003 |
关键词[WOS] | HEAVY-METAL IONS ; HIGH-CAPACITY ADSORPTION ; HEXAVALENT CHROMIUM ; ADSORBENT ; NANOPARTICLES ; KINETICS ; CARBON ; BEADS ; DYE ; THERMODYNAMICS |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Engineering ; Materials Science |
项目资助者 | National Natural Science Foundation of China(21106162) ; National Key Natural Science Foundation of China(21136009) ; Major Project of the National Natural Science Foundation of China(51090382) ; General Research Project of Liaoning Education Department(L2015045) ; Youth Foundation of Dalian Polytechnic University(67007908) |
WOS类目 | Engineering, Chemical ; Materials Science, Multidisciplinary |
WOS记录号 | WOS:000375502100009 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/8306 |
专题 | 资源环境与绿色分离研究组 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Dalian Polytech Univ, Sch Biol Engn, Dalian 116034, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, Xitong,Li, Qian,Yang, Liangrong,et al. Chemically modified magnetic chitosan microspheres for Cr(VI) removal from acidic aqueous solution[J]. PARTICUOLOGY,2016,26:79-86. |
APA | Sun, Xitong,Li, Qian,Yang, Liangrong,&Liu, Huizhou.(2016).Chemically modified magnetic chitosan microspheres for Cr(VI) removal from acidic aqueous solution.PARTICUOLOGY,26,79-86. |
MLA | Sun, Xitong,et al."Chemically modified magnetic chitosan microspheres for Cr(VI) removal from acidic aqueous solution".PARTICUOLOGY 26(2016):79-86. |
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