Speciation of metal phosphonates with the assistance of weak interactions

doi:10.1039/c6dt00643d

QIBEBT-IR > 多相催化转化研究组

	Speciation of metal phosphonates with the assistance of weak interactions
	Hou, Xiaomin 1; Tang, Si-Fu 2
	2016
发表期刊	DALTON TRANSACTIONS
卷号	45 期号:17 页码:7349-7359
摘要	By employing an aromatic methyl substituted V-shaped diphosphonic acid as a ligand, a series of metal diphosphonates, namely [Cu-3(HL)(2)(H2O)(2)][(H2O)(2)] (1), [Cu(H2L)(pyz)(H2O)(2)][(H2O)(2)] (2), [Cu(H2L)(2,2'-bipy)] (3), [Cu(H2L)(4,4'-bipy)(H2O)(2)] (4), [Zn(H2L)(2,2'-bipy)] (5) and [Cd(H2L)(2,2'-bipy)(H2O)][(H2O)(6)] (6), have been synthesized. The structural studies reveal that these compounds exhibit diverse crystal structures. The introduction of the methyl group and pyridine derived auxiliary ligands results in the formation of plenty of C-H center dot center dot center dot O, C-H center dot center dot center dot pi and pi center dot center dot center dot pi interactions, which contribute to the crystallization of metal diphosphonates. It was found that the Zn and Cd containing compounds showed intense intraligand emissions.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c6dt00643d
关键词[WOS]	LUMINESCENT PROPERTIES ; COORDINATION POLYMERS ; PROTON CONDUCTIVITY ; ORGANIC FRAMEWORKS ; AUXILIARY LIGANDS ; COMPLEXES ; ADSORPTION ; PHOSPHATE/PHOSPHONATE ; TRANSFORMATIONS ; DIPHOSPHONATES
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
项目资助者	Natural Science Foundation of China(21171173)
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000375001000023
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/8286
专题	多相催化转化研究组
作者单位	1.Qingdao Agr Univ, Coll Life Sci, Changcheng Rd 700, Qingdao 266109, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Hou, Xiaomin,Tang, Si-Fu. Speciation of metal phosphonates with the assistance of weak interactions[J]. DALTON TRANSACTIONS,2016,45(17):7349-7359.
APA	Hou, Xiaomin,&Tang, Si-Fu.(2016).Speciation of metal phosphonates with the assistance of weak interactions.DALTON TRANSACTIONS,45(17),7349-7359.
MLA	Hou, Xiaomin,et al."Speciation of metal phosphonates with the assistance of weak interactions".DALTON TRANSACTIONS 45.17(2016):7349-7359.