A ribbon-like ultramicroporous conjugated polycarbazole network for gas storage and separation

doi:10.1039/c5nj02567b

QIBEBT-IR > 先进有机功能材料研究组

	A ribbon-like ultramicroporous conjugated polycarbazole network for gas storage and separation
	Qiao, Shanlin 1,2; Wei, Huan 1; Wang, Ting 2; Huang, Wei 2; Gu, Chunyang 2; Yang, Renqiang 2; Li, Xiaoyun 1
	2016
发表期刊	NEW JOURNAL OF CHEMISTRY
卷号	40 期号:4 页码:3172-3176
摘要	A new ultramicroporous conjugated network, P-TCzTAT, enriched with propeller-like carbazole building blocks was designed and synthesized by FeCl3 oxidative coupling polymerization at room temperature. The adsorption isotherm of N-2 reveals that the polymer features a high Brunauer-Emmett-Teller (BET) specific surface area of 1028 m(2) g(-1) and a predominantly narrow pore width of 0.54 nm. The ultramicroporous polymer has strong affinity for CO2, with high sorption abilities of 18.15% at 273 K and 1.1 bar and 10.69% at 273 K/1.1 bar and 298 K/1.1 bar, which can be ascribed to not only its optimal fraction of ultramicropores but also its high nitrogen content derived from the carbazole components. P-TCzTAT also exhibited potential application in gas storage and in CO2/CH4 and CO2/N-2 gas separation.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c5nj02567b
关键词[WOS]	COVALENT ORGANIC FRAMEWORKS ; SURFACE-AREA ; CO2 CAPTURE ; CARBON-DIOXIDE ; MICROPOROUS POLYMERS ; ENERGY APPLICATIONS ; HYDROGEN STORAGE ; ACTIVATED CARBON ; PORE-SIZE ; ADSORPTION
收录类别	SCI ; IC
语种	英语
WOS研究方向	Chemistry
项目资助者	National Natural Science Foundation of China(21274161 ; Ministry of Science and Technology of China(2010DFA52310) ; 51173199 ; 51303197 ; 51573205)
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000373993600027
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/8261
专题	先进有机功能材料研究组
作者单位	1.Hebei Univ Sci & Technol, Inst Chem Ind & Pharmaceut Engn, Shijiazhuang 050000, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Qiao, Shanlin,Wei, Huan,Wang, Ting,et al. A ribbon-like ultramicroporous conjugated polycarbazole network for gas storage and separation[J]. NEW JOURNAL OF CHEMISTRY,2016,40(4):3172-3176.
APA	Qiao, Shanlin.,Wei, Huan.,Wang, Ting.,Huang, Wei.,Gu, Chunyang.,...&Li, Xiaoyun.(2016).A ribbon-like ultramicroporous conjugated polycarbazole network for gas storage and separation.NEW JOURNAL OF CHEMISTRY,40(4),3172-3176.
MLA	Qiao, Shanlin,et al."A ribbon-like ultramicroporous conjugated polycarbazole network for gas storage and separation".NEW JOURNAL OF CHEMISTRY 40.4(2016):3172-3176.