QIBEBT-IR  > 膜分离与催化团队
NiCo nanoalloy encapsulated in graphene layers for improving hydrogen storage properties of LiAlH4
Jiao, Chengli1,2,3,4; Sun, Lixian2,3; Xu, Fen2,3; Liu, Shu-Sheng5; Zhang, Jian4; Jiang, Xia4; Yang, Lini6
2016-06-07
Source PublicationSCIENTIFIC REPORTS
Volume6
AbstractNiCo nanoalloy (4-6 nm) encapsulated in grapheme layers (NiCo@G) has been prepared by thermolysis of a 3D bimetallic complex CoCo[Ni(EDTA)](2)center dot 4H(2)O and successfully employed as a catalyst to improve the dehydrogenation performances of LiAlH4 by solid ball-milling. NiCo@G presents a superior catalytic effect on the dehydrogenation of LiAlH4. For LiAlH4 doped with 1 wt% NiCo@G (LiAlH4-1 wt% NiCo@G), the onset dehydrogenation temperature of LiAlH4 is as low as 43 degrees C, which is 109 degrees C lower than that of pristine LiAlH4. 7.3 wt% of hydrogen can be released from LiAlH4-1 wt% NiCo@G at 150 degrees C within 60 min. The activation energies of LiAlH4 dehydrogenation are extremely reduced by 1 wt% NiCo@G doping.
SubtypeArticle
WOS HeadingsScience & Technology
DOI10.1038/srep27429
WOS KeywordTI-DOPED LIALH4 ; DEHYDROGENATION BEHAVIOR ; MWCNTS ADDITION ; NANOPARTICLES ; CATALYSTS ; PERFORMANCE ; RELEASE ; NANOCRYSTALS ; DESORPTION ; STABILITY
Indexed BySCI
Language英语
WOS Research AreaScience & Technology - Other Topics
Funding OrganizationNational Natural Science Foundation of China(21403267 ; Shandong Postdoctoral Innovation Program(201303065) ; Guangxi Natural Science Foundation(2014jjDA20005 ; Guangxi Key Laboratory of Information Materials(1210908-217-Z) ; Guangxi Scientific Technology Team(2012GXNSFGA06002 ; 21373215 ; 2014jjAA60035) ; 2015GXNSFFA139002) ; 51361005 ; U1501242 ; 21173111 ; 51371060 ; 51201042 ; 51461010 ; 51201041)
WOS SubjectMultidisciplinary Sciences
WOS IDWOS:000377177000001
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.qibebt.ac.cn/handle/337004/8237
Collection膜分离与催化团队
Affiliation1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China
2.Guilin Univ Elect Technol, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R China
3.Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guangxi Collaborat Innovat Ctr Struct & Property, Guilin 541004, Peoples R China
4.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
5.Kyushu Univ, INAMORI Frontier Res Ctr, Nishi Ku, Fukuoka 8190395, Japan
6.Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China
Recommended Citation
GB/T 7714
Jiao, Chengli,Sun, Lixian,Xu, Fen,et al. NiCo nanoalloy encapsulated in graphene layers for improving hydrogen storage properties of LiAlH4[J]. SCIENTIFIC REPORTS,2016,6.
APA Jiao, Chengli.,Sun, Lixian.,Xu, Fen.,Liu, Shu-Sheng.,Zhang, Jian.,...&Yang, Lini.(2016).NiCo nanoalloy encapsulated in graphene layers for improving hydrogen storage properties of LiAlH4.SCIENTIFIC REPORTS,6.
MLA Jiao, Chengli,et al."NiCo nanoalloy encapsulated in graphene layers for improving hydrogen storage properties of LiAlH4".SCIENTIFIC REPORTS 6(2016).
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Jiao, Chengli]'s Articles
[Sun, Lixian]'s Articles
[Xu, Fen]'s Articles
Baidu academic
Similar articles in Baidu academic
[Jiao, Chengli]'s Articles
[Sun, Lixian]'s Articles
[Xu, Fen]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Jiao, Chengli]'s Articles
[Sun, Lixian]'s Articles
[Xu, Fen]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.