A sustainable process for the production of 2-methyl-1,4-butanediol by hydrogenation of biomass-derived itaconic acid | |
Liu, Xiaoran1,2; Wang, Xicheng1; Liu, Qiang1,2; Xu, Guoqiang1; Li, Xuemin1; Mu, Xindong1 | |
2016-10-01 | |
发表期刊 | CATALYSIS TODAY |
卷号 | 274页码:88-93 |
摘要 | Pd-ReOx/C catalysts with different Re contents were prepared and employed to catalyze the aqueous hydrogenation of itaconic acid in this study. The Pd-ReOx/C catalysts were characterized by XRD, TEM, BET, NH3-TPD and H-2-TPR. Results showed that the addition of ReOx species in supported Pd catalysts promoted the direct conversion of itaconic acid to 2-methyl-1,4-butanediol. The promoting effect was ascribed to the interaction between Pd and ReOx species, as has been proved by the characterizations. A 2-methyl-1,4-butanediol yield of above 80% could be obtained over Pd-3ReO(x)/C under the reaction condition of 180 degrees C, 4 MPa H-2. (C) 2016 Elsevier B.V. All rights reserved. |
文章类型 | Article |
关键词 | Biomass Itaconic Acid Hydrogenation 2-methyl-1 Pd-reox/c 4-butanediol |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1016/j.cattod.2016.01.041 |
关键词[WOS] | AQUEOUS-PHASE HYDROGENATION ; SUCCINIC ACID ; LIGNOCELLULOSIC BIOMASS ; GAMMA-BUTYROLACTONE ; PD/TIO2 CATALYSTS ; HYDROGENOLYSIS ; CHEMICALS ; PLATFORM ; CARBON ; TETRAHYDROFURAN |
收录类别 | SCI ; ISTP |
语种 | 英语 |
WOS研究方向 | Chemistry ; Engineering |
WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
WOS记录号 | WOS:000377388300015 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/8235 |
专题 | 绿色化学催化研究组 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Xiaoran,Wang, Xicheng,Liu, Qiang,et al. A sustainable process for the production of 2-methyl-1,4-butanediol by hydrogenation of biomass-derived itaconic acid[J]. CATALYSIS TODAY,2016,274:88-93. |
APA | Liu, Xiaoran,Wang, Xicheng,Liu, Qiang,Xu, Guoqiang,Li, Xuemin,&Mu, Xindong.(2016).A sustainable process for the production of 2-methyl-1,4-butanediol by hydrogenation of biomass-derived itaconic acid.CATALYSIS TODAY,274,88-93. |
MLA | Liu, Xiaoran,et al."A sustainable process for the production of 2-methyl-1,4-butanediol by hydrogenation of biomass-derived itaconic acid".CATALYSIS TODAY 274(2016):88-93. |
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