Benzopyrazinoisoindigo or Its Reduced Form? Synthesis, Clarification, and Application in Field-Effect Transistors
Wang, Xiao1; Zhao, Zhiyuan2,3; Ai, Na4; Pei, Jian4; Liu, Yunqi3; Wan, Xiaobo1
2016-05-01
发表期刊EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
期号15页码:2603-2607
摘要Benzopyrazinoisoindigo, a pigment reported 40 years ago, should be a good candidate for n-type semiconductors if the reported structure is correct. Reinvestigation of this molecule revealed that it is actually (4H,4'H)-benzopyrazinoisoindigo, which could be considered as the reduced form of benzopyrazinoisoindigo, and hence, it is a good candidate for p-type semiconductors. The route toward the synthesis of this molecule was optimized, and a mechanism was accordingly proposed. A field-effect transistor based on this material showed a hole mobility up to 2.5 x 10(-2) cm(2) V-1 s(-1).
文章类型Article
关键词Conducting Materials Dyes/pigments Organic Field-effect Transistors Semiconductors Synthetic Methods
WOS标题词Science & Technology ; Physical Sciences
DOI10.1002/ejoc.201600363
关键词[WOS]ORGANIC SEMICONDUCTORS ; BUILDING-BLOCK ; SOLAR-CELLS ; DESIGN ; POLYMERS ; MOBILITY
收录类别SCI
语种英语
WOS研究方向Chemistry
项目资助者"100 Talents Program" from the Chinese Academy of Sciences ; National Science Foundation of China (NSFC)(21402220 ; 51573204)
WOS类目Chemistry, Organic
WOS记录号WOS:000377251800004
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/8227
专题生物基及仿生高分子材料团队(过去)
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China
2.NE Normal Univ, Changchun 130024, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
4.Peking Univ, Beijing 100049, Peoples R China
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Wang, Xiao,Zhao, Zhiyuan,Ai, Na,et al. Benzopyrazinoisoindigo or Its Reduced Form? Synthesis, Clarification, and Application in Field-Effect Transistors[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2016(15):2603-2607.
APA Wang, Xiao,Zhao, Zhiyuan,Ai, Na,Pei, Jian,Liu, Yunqi,&Wan, Xiaobo.(2016).Benzopyrazinoisoindigo or Its Reduced Form? Synthesis, Clarification, and Application in Field-Effect Transistors.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(15),2603-2607.
MLA Wang, Xiao,et al."Benzopyrazinoisoindigo or Its Reduced Form? Synthesis, Clarification, and Application in Field-Effect Transistors".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .15(2016):2603-2607.
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