Benzopyrazinoisoindigo or Its Reduced Form? Synthesis, Clarification, and Application in Field-Effect Transistors

doi:10.1002/ejoc.201600363

	Benzopyrazinoisoindigo or Its Reduced Form? Synthesis, Clarification, and Application in Field-Effect Transistors
	Wang, Xiao1 ; Zhao, Zhiyuan 2,3; Ai, Na 4; Pei, Jian 4; Liu, Yunqi 3; Wan, Xiaobo 1
	2016-05-01
发表期刊	EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
期号	15 页码:2603-2607
摘要	Benzopyrazinoisoindigo, a pigment reported 40 years ago, should be a good candidate for n-type semiconductors if the reported structure is correct. Reinvestigation of this molecule revealed that it is actually (4H,4'H)-benzopyrazinoisoindigo, which could be considered as the reduced form of benzopyrazinoisoindigo, and hence, it is a good candidate for p-type semiconductors. The route toward the synthesis of this molecule was optimized, and a mechanism was accordingly proposed. A field-effect transistor based on this material showed a hole mobility up to 2.5 x 10(-2) cm(2) V-1 s(-1).
文章类型	Article
关键词	Conducting Materials Dyes/pigments Organic Field-effect Transistors Semiconductors Synthetic Methods
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1002/ejoc.201600363
关键词[WOS]	ORGANIC SEMICONDUCTORS ; BUILDING-BLOCK ; SOLAR-CELLS ; DESIGN ; POLYMERS ; MOBILITY
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
项目资助者	"100 Talents Program" from the Chinese Academy of Sciences ; National Science Foundation of China (NSFC)(21402220 ; 51573204)
WOS类目	Chemistry, Organic
WOS记录号	WOS:000377251800004
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/8227
专题	生物基及仿生高分子材料团队（过去）
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.NE Normal Univ, Changchun 130024, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 4.Peking Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wang, Xiao,Zhao, Zhiyuan,Ai, Na,et al. Benzopyrazinoisoindigo or Its Reduced Form? Synthesis, Clarification, and Application in Field-Effect Transistors[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2016(15):2603-2607.
APA	Wang, Xiao,Zhao, Zhiyuan,Ai, Na,Pei, Jian,Liu, Yunqi,&Wan, Xiaobo.(2016).Benzopyrazinoisoindigo or Its Reduced Form? Synthesis, Clarification, and Application in Field-Effect Transistors.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(15),2603-2607.
MLA	Wang, Xiao,et al."Benzopyrazinoisoindigo or Its Reduced Form? Synthesis, Clarification, and Application in Field-Effect Transistors".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .15(2016):2603-2607.