High Conductive Two-Dimensional Covalent Organic Framework for Lithium Storage with Large Capacity

doi:10.1021/acsami.5b12370

QIBEBT-IR > 碳基材料与能源应用研究组

	High Conductive Two-Dimensional Covalent Organic Framework for Lithium Storage with Large Capacity
	Yang, Hui 1,3; Zhang, Shengliang 2,3; Han, Liheng 1; Zhang, Zhou 1; Xue, Zheng 1; Gao, Juan 1,3; Li, Yongjun 1; Huang, Changshui 2; Yi, Yuanping 1; Liu, Huibiao 1; Li, Yuliang 1
	2016-03-02
发表期刊	ACS APPLIED MATERIALS & INTERFACES
卷号	8 期号:8 页码:5366-5375
摘要	A high conductive 2D COF polyporphyrin (TThPP) linked by 4-thiophenephenyl groups was synthesized through an in situ chemical oxidative polymerization on the surface of copper foil. The TThPP films were used as the anode of lithium-ion battery, which exhibited high specific capacities, excellent rate performances, and long cycle lives due to the alignment of 2D polyporphyrin nanosheets, and they (i) can highly efficiently adsorb Li atoms, (ii) have short-ended paths for the fast lithium ion diffusion, and (iii) open nanopores holding electrolyte. The reversible capacity is up to 666 mAh/g. This is the first example of an organic 2D COF for an anode of lithium-ion battery and represents an important step toward the use of COFs in the next-generation high-performance lithium ion battery.
文章类型	Article
关键词	2d Cof Polyporphyrin High Conductive Lithium Storage High Capacity
WOS标题词	Science & Technology ; Technology
DOI	10.1021/acsami.5b12370
关键词[WOS]	ION BATTERIES ; PHOTOPHYSICAL PROPERTIES ; PORPHYRIN ARRAYS ; HYDROGEN STORAGE ; THIN-FILMS ; PERFORMANCE ; CATHODE ; CRYSTALLINE ; POLYMERS ; ELECTRON
收录类别	SCI
语种	英语
WOS研究方向	Science & Technology - Other Topics ; Materials Science
项目资助者	National Basic Research 973 Program of China(2012CB932901) ; National Nature Science Foundation of China(51573191 ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDB12010100) ; 21373235 ; 21290190)
WOS类目	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000371453600036
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/8059
专题	碳基材料与能源应用研究组
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, BNLMS, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Yang, Hui,Zhang, Shengliang,Han, Liheng,et al. High Conductive Two-Dimensional Covalent Organic Framework for Lithium Storage with Large Capacity[J]. ACS APPLIED MATERIALS & INTERFACES,2016,8(8):5366-5375.
APA	Yang, Hui.,Zhang, Shengliang.,Han, Liheng.,Zhang, Zhou.,Xue, Zheng.,...&Li, Yuliang.(2016).High Conductive Two-Dimensional Covalent Organic Framework for Lithium Storage with Large Capacity.ACS APPLIED MATERIALS & INTERFACES,8(8),5366-5375.
MLA	Yang, Hui,et al."High Conductive Two-Dimensional Covalent Organic Framework for Lithium Storage with Large Capacity".ACS APPLIED MATERIALS & INTERFACES 8.8(2016):5366-5375.