QIBEBT-IR  > 工业生物燃气研究组
Heterogeneous Transesterification of Dimethyl Carbonate and Phenol to Diphenyl Carbonate over Vanadium Pentoxide Microstructures
Wang, Qiang1,2; Sun, Ming Ming1,2; Guo, Ming1,2; Luo, Sheng Jun3; Li, Chun Hong4,5; Hu, Chang Wen6
2015
发表期刊INTEGRATED FERROELECTRICS
卷号164期号:1页码:154-164
摘要Vanadium pentoxide (V2O5) microstructures were synthesized by calcining acidtreated NH4VO3 at 773 K in air, which were used as heterogeneous catalysts for the synthesis of diphenyl carbonate (DPC) by the transesterification of dimethyl carbonate (DMC) with phenol. The effects of the types of acid and the transesterification reaction time on catalytic activities were investigated. Under the conditions of reaction temperature of 453 K, a catalyst amount of 0.2% (molar ratio to phenol), molar ratio of DMC/phenol of 1:2 and a reaction time of 13 h, the maximum conversion of DMC and total yields of methyl phenyl carbonate (MPC) and DPC were 23.23 and 23.44%, respectively. The selectivity to the transesterification was nearly 100%. The plausible mechanism of the transesterification catalyzed by the V2O5 microstructures was also probed preliminarily. X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) characteristics of the catalyst samples had been recorded.
文章类型Article
关键词Vanadium Pentoxide Transesterification Diphenyl Carbonate Catalytic Activities
WOS标题词Science & Technology ; Technology ; Physical Sciences
DOI10.1080/10584587.2015.1045399
关键词[WOS]ZINC DOUBLE OXIDE ; OXIDATIVE DEHYDROGENATION ; MOO3/SIO2 CATALYSTS ; OXALATE ; SILICA ; PARTICLES ; METHANOL ; DIALKYL ; PROPANE ; ACID
收录类别SCI
语种英语
WOS研究方向Engineering ; Physics
项目资助者Natural Science Foundation of China (NSFC)(21471103 ; 111 Project(B07012) ; Project of Excellent Talents of Beijing(203135407707) ; Project of Research Base Construction of Beijing Municipal Education Commission ; 51002180 ; 21001074 ; 10876002 ; 91022006 ; 20973023)
WOS类目Engineering, Electrical & Electronic ; Physics, Applied ; Physics, Condensed Matter
WOS记录号WOS:000371295300020
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/8053
专题工业生物燃气研究组
作者单位1.Capital Normal Univ, Lab Microsized Funct Mat, Beijing 100048, Peoples R China
2.Capital Normal Univ, Coll Elementary Educ, Beijing 100048, Peoples R China
3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Shandong Ind Engn Lab Biogas Prod & Utilizat, Qingdao 266101, Peoples R China
4.Chinese Acad Sci, Natl Lab Superconduct, Inst Phys, Beijing 100190, Peoples R China
5.Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
6.Beijing Inst Technol, Dept Chem, Inst Chem Phys, Key Lab Cluster Sci,Minist Educ China, Beijing 100081, Peoples R China
推荐引用方式
GB/T 7714
Wang, Qiang,Sun, Ming Ming,Guo, Ming,et al. Heterogeneous Transesterification of Dimethyl Carbonate and Phenol to Diphenyl Carbonate over Vanadium Pentoxide Microstructures[J]. INTEGRATED FERROELECTRICS,2015,164(1):154-164.
APA Wang, Qiang,Sun, Ming Ming,Guo, Ming,Luo, Sheng Jun,Li, Chun Hong,&Hu, Chang Wen.(2015).Heterogeneous Transesterification of Dimethyl Carbonate and Phenol to Diphenyl Carbonate over Vanadium Pentoxide Microstructures.INTEGRATED FERROELECTRICS,164(1),154-164.
MLA Wang, Qiang,et al."Heterogeneous Transesterification of Dimethyl Carbonate and Phenol to Diphenyl Carbonate over Vanadium Pentoxide Microstructures".INTEGRATED FERROELECTRICS 164.1(2015):154-164.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Wang, Qiang]的文章
[Sun, Ming Ming]的文章
[Guo, Ming]的文章
百度学术
百度学术中相似的文章
[Wang, Qiang]的文章
[Sun, Ming Ming]的文章
[Guo, Ming]的文章
必应学术
必应学术中相似的文章
[Wang, Qiang]的文章
[Sun, Ming Ming]的文章
[Guo, Ming]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。