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Effect of hierarchical crystal structures on the properties of cobalt catalysts for Fischer-Tropsch synthesis
Wang, Yuelun1; Jiang, Yuan1; Huang, Jun1; Liang, Jing1; Wang, Hui2; Li, Zhuo2; Wu, Jinhu2; Li, Min1; Zhao, Yunpeng1; Niu, Jiachen1
2016-06-15
发表期刊FUEL
卷号174页码:17-24
摘要Mesoporous ZSM-5 was synthesized using double-template method and its application in FischerTropsch synthesis (FTS) was studied. By comparison, ZSM-5 and SBA-15 were also prepared. The results demonstrated that the catalysts with bimodal structure and moderate acidity showed higher C5-18 selectivity with relatively lower CH4 selectivity, while higher C5-12 selectivity over Co/ZSM-5 catalyst and higher C12-18 selectivity over Co/SBA-15 catalyst were observed, respectively. Cobalt loaded on crystalline mesoporous ZSM-5 showed the lowest deactivated rate, which suggested that such bimodal structure was favor to the stabilization of cobalt particles. As a result of lower hydrothermal stability of mesopority, Co/SBA-15 catalyst had the fastest deactivation. (c) 2016 Elsevier Ltd. All rights reserved.
文章类型Article
关键词Fischer-tropsch Synthesis Hierarchical Zeolites Crystalline Cobalt Catalyst
WOS标题词Science & Technology ; Technology
DOI10.1016/j.fuel.2016.01.045
关键词[WOS]SUPPORTED RUTHENIUM NANOPARTICLES ; C-5-C-11 ISOPARAFFINS ; CO HYDROGENATION ; PORE-SIZE ; ZEOLITE ; DEACTIVATION ; PERFORMANCE ; MESOPOROSITY ; SELECTIVITY ; DISPERSION
收录类别SCI
语种英语
WOS研究方向Energy & Fuels ; Engineering
项目资助者scientific research program for the frontier of subject - China University of Mining and Technology(2015XKMS044) ; Innovative Experimental program for College students in Jiangsu province(201510290022X) ; Foundation of industrialization, teaching and research cooperation program of Jiangsu province(BY2014091) ; Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
WOS类目Energy & Fuels ; Engineering, Chemical
WOS记录号WOS:000370530600003
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/8014
专题热化学转化研究组
作者单位1.China Univ Min & Technol, Minist Educ, Key Lab Coal Proc & Efficient Utilizat, Xuzhou 221116, Jiangsu, Peoples R China
2.Chinese Acad Sci, Key Lab Biofuel, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
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GB/T 7714
Wang, Yuelun,Jiang, Yuan,Huang, Jun,et al. Effect of hierarchical crystal structures on the properties of cobalt catalysts for Fischer-Tropsch synthesis[J]. FUEL,2016,174:17-24.
APA Wang, Yuelun.,Jiang, Yuan.,Huang, Jun.,Liang, Jing.,Wang, Hui.,...&Niu, Jiachen.(2016).Effect of hierarchical crystal structures on the properties of cobalt catalysts for Fischer-Tropsch synthesis.FUEL,174,17-24.
MLA Wang, Yuelun,et al."Effect of hierarchical crystal structures on the properties of cobalt catalysts for Fischer-Tropsch synthesis".FUEL 174(2016):17-24.
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