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A new microporous layer material to improve the performance and durability of polymer electrolyte membrane fuel cells
Jiang, Yongyi1,2; Hao, Jinkai1,2; Hou, Ming1; Zhang, Hongjie1,2; Li, Xiaojin3; Shao, Zhigang1; Yi, Baolian1
2015
发表期刊RSC ADVANCES
卷号5期号:126页码:104095-104100
摘要Antimony doped tin oxide (ATO), a kind of semiconducting nanocrystalline material, has excellent electrochemical stability but poor electrical conductivity. Herein, ATO nanocomposites with carbon coatings are prepared by immersing ATO nano-material into dopamine solution, and then thermal treatment to improve the electrical conductivity of the ATO material. The morphology and microstructure of ATO@C/N nanocomposites are characterized using a scanning electron microscope and transmission electron microscopy. The GDLs with the MPL prepared from ATO@C/N nanocomposites are characterized by through-plane resistance testing, mercury intrusion porosimetry and surface contact angle measurement. The results of the above show that ATO@C/N nanocomposites with a 2.16 nm thick carbon coating enhance the electrical conductivity of ATO nanocrystals and exhibit higher electrochemical stability. Further, the performance of MEA fabricated with ATO@C/N as the cathode MPL is evaluated. The maximum power density approaches 1000 mW cm(-2), and a slight difference in cell performance is observed compared to XC-72.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c5ra18552a
关键词[WOS]GAS-DIFFUSION LAYER ; DOPED TIN OXIDE ; HIGH HUMIDITY ; CATALYST ; CORROSION ; SUPPORT ; PEMFC ; AGENT ; FE3O4
收录类别SCI
语种英语
WOS研究方向Chemistry
项目资助者National Key Basic Research Program of China (973 Program)(2012CB215505) ; National Natural Science Foundation of China(61433013)
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000366433700038
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文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/6843
专题电化学过程研究组
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Syst & Engn Lab, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
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Jiang, Yongyi,Hao, Jinkai,Hou, Ming,et al. A new microporous layer material to improve the performance and durability of polymer electrolyte membrane fuel cells[J]. RSC ADVANCES,2015,5(126):104095-104100.
APA Jiang, Yongyi.,Hao, Jinkai.,Hou, Ming.,Zhang, Hongjie.,Li, Xiaojin.,...&Yi, Baolian.(2015).A new microporous layer material to improve the performance and durability of polymer electrolyte membrane fuel cells.RSC ADVANCES,5(126),104095-104100.
MLA Jiang, Yongyi,et al."A new microporous layer material to improve the performance and durability of polymer electrolyte membrane fuel cells".RSC ADVANCES 5.126(2015):104095-104100.
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