Tuning the catalytic selectivity in biomass-derived succinic acid hydrogenation on FeOx-modified Pd catalysts

doi:10.1039/c5ta03843j

QIBEBT-IR > 绿色化学催化研究组

	Tuning the catalytic selectivity in biomass-derived succinic acid hydrogenation on FeOx-modified Pd catalysts
	Liu, Xiaoran 1,3; Wang, Xicheng1 ; Xu, Guoqiang1 ; Liu, Qiang 1,3; Mu, Xindong 1; Liu, Haichao 2
	2015
发表期刊	JOURNAL OF MATERIALS CHEMISTRY A
卷号	3 期号:46 页码:23560-23569
摘要	Succinic acid is an important biomass-derived C4 building block and is ready to be converted into various value-added chemicals. Here we report that tunable selectivity for the formation of 1,4-butanediol, gamma-butyrolactone and tetrahydrofuran from aqueous succinic acid hydrogenation could be achieved on FeOx-promoted Pd/C catalysts. Fe was found to be an efficient promoter for the succinic acid hydrogenation, which not only improved the activity of the catalysts but also tuned the product distribution. Succinic acid could be transformed into 1,4-butanediol with a yield of over 70% in the presence of the Pd5FeO(x)/C catalyst under the relatively mild conditions of 200 degrees C and 5 MPa H-2. The reaction pathway was also proposed according to the reaction and characterization results.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences ; Technology
DOI	10.1039/c5ta03843j
关键词[WOS]	AQUEOUS-PHASE HYDROGENATION ; BIMETALLIC CATALYSTS ; GAMMA-BUTYROLACTONE ; PD/TIO2 CATALYSTS ; CHEMICALS ; HYDROGENOLYSIS ; 1,4-BUTANEDIOL ; HYDRODECHLORINATION ; PD-FE/SIO2 ; CONVERSION
收录类别	SCI
语种	英语
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
项目资助者	National Natural Science Foundation of China(21273260 ; Shandong Provincial Natural Science Foundation for Distinguished Young Scholar, China(JQ201305) ; "135" Projects Fund of CAS-QIBEBT Director Innovation Foundation ; Chinese Academy of Sciences ; 21433001)
WOS类目	Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS记录号	WOS:000365216000057
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6801
专题	绿色化学催化研究组
作者单位	1.Chinese Acad Sci, Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Liu, Xiaoran,Wang, Xicheng,Xu, Guoqiang,et al. Tuning the catalytic selectivity in biomass-derived succinic acid hydrogenation on FeOx-modified Pd catalysts[J]. JOURNAL OF MATERIALS CHEMISTRY A,2015,3(46):23560-23569.
APA	Liu, Xiaoran,Wang, Xicheng,Xu, Guoqiang,Liu, Qiang,Mu, Xindong,&Liu, Haichao.(2015).Tuning the catalytic selectivity in biomass-derived succinic acid hydrogenation on FeOx-modified Pd catalysts.JOURNAL OF MATERIALS CHEMISTRY A,3(46),23560-23569.
MLA	Liu, Xiaoran,et al."Tuning the catalytic selectivity in biomass-derived succinic acid hydrogenation on FeOx-modified Pd catalysts".JOURNAL OF MATERIALS CHEMISTRY A 3.46(2015):23560-23569.