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Pd(PrSO3)(2)@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C-X activations in air and water
Rostamnia, Sadegh1; Rahmani, Turaj1; Xin, Hongchuan2
2015-12-25
发表期刊JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
卷号32页码:218-224
摘要A series of ordered mesoporous organic-inorganic hybrid material are designed by using the SO3H-functionalized SBA-15 [(PdX2@SBA-15/SO3H or Pd(PrSO3)(2)@SBA-15) and (Pd-NPs@SBA-15/SO3H or Pd-NPs(PrSO3)@SBA-15)] as solid supports for palladium ions. Among them, the encapsulated Pd(MeCN)(2)Cl-2 into the SBA-15/SO3H and Pd-NPs@SBA-15/SO3H exhibit higher activity and selectivity toward Suzuki cross-coupling reaction in aerobic condition and water/DMF solvent. These heterogeneous palladium precatalysts could be separated from the reaction mixture and reused at least 11 times. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
文章类型Article
关键词Pd(Prso3)(2)@sba-15 Pd-nps(Prso3)@sba-15 Interface Catalyst Suzuld C-x Activations
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.jiec.2015.08.019
关键词[WOS]MIYAURA COUPLING REACTIONS ; MAGNETIC NANOPARTICLES ; NANOPOROUS SILICA ; MESOPOROUS SILICA ; GREEN ; PALLADIUM ; HECK ; EFFICIENT ; HYDROGENATION ; NANOCOMPOSITE
收录类别SCI
语种英语
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号WOS:000365368200028
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/6798
专题科技处
作者单位1.Univ Maragheh, Fac Sci, Dept Chem, Organ & Nano Grp, Maragheh 5518183111, Iran
2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China
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Rostamnia, Sadegh,Rahmani, Turaj,Xin, Hongchuan. Pd(PrSO3)(2)@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C-X activations in air and water[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,2015,32:218-224.
APA Rostamnia, Sadegh,Rahmani, Turaj,&Xin, Hongchuan.(2015).Pd(PrSO3)(2)@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C-X activations in air and water.JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,32,218-224.
MLA Rostamnia, Sadegh,et al."Pd(PrSO3)(2)@SBA-15 and Pd-NPs(PrSO3)@SBA-15 hybrid materials: A highly active, reusable, and selective interface catalyst for C-X activations in air and water".JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 32(2015):218-224.
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