Transesterification of dimethyl carbonate with phenol to diphenyl carbonate over hexagonal Mg(OH)(2) nanoflakes

doi:10.1039/c4qi00113c

QIBEBT-IR > 工业生物燃气研究组

	Transesterification of dimethyl carbonate with phenol to diphenyl carbonate over hexagonal Mg(OH)(2) nanoflakes
	Wang, Qiang 1,2; Li, Chunhong 3,4; Guo, Ming 1,2; Luo, Shengjun 5; Hu, Changwen 6,7
	2015
发表期刊	INORGANIC CHEMISTRY FRONTIERS
卷号	2 期号:1 页码:47-54
摘要	Hexagonal Mg(OH)(2) nanoflakes were synthesized via a hydrothermal method in the presence of polyethylene glycol 20000 (PEG-20000). X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) were applied to characterize the composition, morphologies and structure of the Mg(OH)(2) nanoflakes. Brunauer-Emmett-Teller (BET) analysis was performed to investigate the porous structure and surface area of the as-obtained nanoflakes. The transesterification of dimethyl carbonate (DMC) with phenol to produce diphenyl carbonate (DPC) was carried out over the hexagonal Mg(OH)(2) nanoflakes. The evaluation results showed that the hexagonal Mg(OH)(2) nanoflakes had better activity and excellent selectivity to target products compared with many conventional ester exchange catalysts. Compared with other catalysts, such as AlCl3, ZnCl2, and irregular Mg(OH)(2) synthesized via a hydrothermal method without PEG-20000, which all have been widely used as catalysts for this transesterification reaction, Mg(OH)(2) nanoflakes were more stable and showed a relatively high activity with a low catalyst amount. The transesterification reaction process was also analyzed with the classic thermodynamic theory, and when the reaction was carried out at 453 K, with a molar ratio of phenol to DMC of 2 : 1, a reaction time of 13 h, and a catalyst amount of 0.2% (molar ratio to phenol), the selectivity of the transesterification reaction reached 92.3%. Moreover, the deactivated hexagonal Mg(OH)(2) nanoflakes could be easily reactivated by calcination under vacuum, and the regenerated Mg(OH)(2) nanoflakes showed the catalytic activity almost as high as that of the fresh sample.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c4qi00113c
关键词[WOS]	ZINC DOUBLE OXIDE ; MAGNESIUM-HYDROXIDE ; CATALYST ; OXALATE ; PARTICLES ; DIALKYL ; SILICA ; PHASE ; HEAT ; ACID
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
项目资助者	Natural Science Foundation of China (NSFC)(21471103 ; 111 Project(B07012) ; Fundamental Research Funds for the Central Universities(2013NT13) ; Project of Excellent Talents of Beijing(203135407707) ; Scientific Research Base Development Program of the Beijing Municipal Commission of Education ; 21471100 ; 51002180 ; 21001074 ; 20731002 ; 20871016 ; 10876002 ; 91022006 ; 20973023)
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000364544300006
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6777
专题	工业生物燃气研究组
作者单位	1.Capital Normal Univ, Lab Microsized Funct Mat, Beijing, Peoples R China 2.Capital Normal Univ, Coll Elementary Educ, Beijing, Peoples R China 3.Chinese Acad Sci, Inst Phys, Natl Lab Superconduct, Beijing 100080, Peoples R China 4.Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Beijing, Peoples R China 5.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao, Peoples R China 6.Beijing Inst Technol, Key Lab Cluster Sci, Minist Educ China, Inst Chem Phys, Beijing 100081, Peoples R China 7.Beijing Inst Technol, Dept Chem, Beijing 100081, Peoples R China
推荐引用方式 GB/T 7714	Wang, Qiang,Li, Chunhong,Guo, Ming,et al. Transesterification of dimethyl carbonate with phenol to diphenyl carbonate over hexagonal Mg(OH)(2) nanoflakes[J]. INORGANIC CHEMISTRY FRONTIERS,2015,2(1):47-54.
APA	Wang, Qiang,Li, Chunhong,Guo, Ming,Luo, Shengjun,&Hu, Changwen.(2015).Transesterification of dimethyl carbonate with phenol to diphenyl carbonate over hexagonal Mg(OH)(2) nanoflakes.INORGANIC CHEMISTRY FRONTIERS,2(1),47-54.
MLA	Wang, Qiang,et al."Transesterification of dimethyl carbonate with phenol to diphenyl carbonate over hexagonal Mg(OH)(2) nanoflakes".INORGANIC CHEMISTRY FRONTIERS 2.1(2015):47-54.