| A Green and Efficient Trinitration System for Aromatic Compounds with Bi(NO3)(3)center dot 5H(2)O/[HMIM]ClO4 as Catalyst in HNO3/Ac2O | |
Sun Weizhi1 ; Yu Shitao2; Xian Mo1
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| 2015-10-01 | |
| 发表期刊 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
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| 卷号 | 31期号:5页码:761-765 |
| 摘要 | To investigate the green trinitration method of aromatic compounds, with Lewis acid/ionic liquid as catalyst and HNO3/Ac2O as nitration reagent, a Lewis acid/ionic liquid/HNO3/Ac2O system was established. In various combinations of Lewis acids and ionic liquids, Bi(NO3)3 center dot 5H(2)O/[HMIM]ClO4 proved to be a very efficient catalyst for the trinitration of activated aromatic compounds and reusable for 3 times. Reaction conditions for the trinitration were optimized and yields of the trinitro products were from mild to excellent. This sulfuric acid-free system has the advantages of strong trinitration ability, low environment pollution, low toxicity, low cost and high potential for industrial application. |
| 文章类型 | Article |
| 关键词 | Green Trinitration Aromatic Compound Lewis Acid Ionic Liquid Acetyl Nitrate |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1007/s40242-015-5087-1 |
| 关键词[WOS] | IONIC LIQUIDS ; REGIOSELECTIVE NITRATION ; BISMUTH NITRATE ; ACETYL NITRATE ; SOLVENTS ; PHASE ; METAL ; ACID ; TOLUENE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| WOS记录号 | WOS:000362860000015 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6694 |
| 专题 | 生物基材料组群 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun Weizhi,Yu Shitao,Xian Mo. A Green and Efficient Trinitration System for Aromatic Compounds with Bi(NO3)(3)center dot 5H(2)O/[HMIM]ClO4 as Catalyst in HNO3/Ac2O[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2015,31(5):761-765. |
| APA | Sun Weizhi,Yu Shitao,&Xian Mo.(2015).A Green and Efficient Trinitration System for Aromatic Compounds with Bi(NO3)(3)center dot 5H(2)O/[HMIM]ClO4 as Catalyst in HNO3/Ac2O.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,31(5),761-765. |
| MLA | Sun Weizhi,et al."A Green and Efficient Trinitration System for Aromatic Compounds with Bi(NO3)(3)center dot 5H(2)O/[HMIM]ClO4 as Catalyst in HNO3/Ac2O".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 31.5(2015):761-765. |
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| A Green and Efficien（465KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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