Biomimetic Nitration of Phenols Using Metalloporphyrins/H2O2/NO2 (-) | |
Sun, Weizhi; Liu, Yaojie; Zhang, Haibo; Xian, Mo; Liu, Huizhou | |
2015-11-01 | |
发表期刊 | CATALYSIS LETTERS |
卷号 | 145期号:11页码:1991-1999 |
摘要 | An efficient metalloporphyrins/H2O2/NO2 (-) nitration of phenols has been developed. The total yield of nitrophenol could reach up to 55.1 %, which is about 4 and sixfold higher than that of horse radish peroxidase catalysis and peroxynitrite nitration, respectively. Furthermore, the nitration system attained an enhanced regioselectivity of 1.0 o/p ratio, and exhibited a good substrate scope of monophenols. This protocol is environmentally friendly compared with HNO3/H2SO4 nitration, and stable, inexpensive and organic solvent tolerant compared with enzyme catalytic nitration and peroxynitrite nitration reaction. |
文章类型 | Article |
关键词 | Phenol Nitration Mentalloporphyrin Mimic Enzyme |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1007/s10562-015-1610-8 |
关键词[WOS] | ENZYMATIC NITRATION ; TYROSINE NITRATION ; IRON PORPHYRINS ; PEROXYNITRITE ; OXIDATION ; MANGANESE ; MECHANISM ; PROTEINS |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000361989100008 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6674 |
专题 | 生物基材料组群 |
作者单位 | Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, Weizhi,Liu, Yaojie,Zhang, Haibo,et al. Biomimetic Nitration of Phenols Using Metalloporphyrins/H2O2/NO2 (-)[J]. CATALYSIS LETTERS,2015,145(11):1991-1999. |
APA | Sun, Weizhi,Liu, Yaojie,Zhang, Haibo,Xian, Mo,&Liu, Huizhou.(2015).Biomimetic Nitration of Phenols Using Metalloporphyrins/H2O2/NO2 (-).CATALYSIS LETTERS,145(11),1991-1999. |
MLA | Sun, Weizhi,et al."Biomimetic Nitration of Phenols Using Metalloporphyrins/H2O2/NO2 (-)".CATALYSIS LETTERS 145.11(2015):1991-1999. |
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