生物基材料组群知识库

QQ客服 官方微博 反馈留言

	Comparative Study on the Catalytic Properties of Amino-Functionalized SilicaMaterials for the Transesterification of Dimethyl Oxalate With Phenol
	Liu, Y (Liu, Yan)1; Zhao, GM (Zhao, Guoming)2; Zhu, WC (Zhu, Wanchun)1; Wang, J (Wang, Jing)1; Liu, G (Liu, Gang)1; Zhang, WX (Zhang, Wenxiang)1; Jia, MJ (Jia, Mingjun)1
	2010
发表期刊	JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
ISSN	0103-5053
卷号	21期号:12页码:2254-2261
摘要	A series of hybrid mesoporous MCM-41 materials containing different amino groups (such as 3-aminopropyl (AP-), (2-aminoethylamino) propyl (AAP-), or [2-(2-aminoethylamino) ethylamino] propyl (AEP-) group) were prepared by a post-grafting method, and characterized by means of X-ray powder diffraction (XRD), N(2) adsorption, Fourier transform-infrared spectroscopy (FT-IR) and temperature-programmed desorption of CO(2) (CO(2)-TPD). The catalytic properties of these hybrid materials were investigated for the transesterification of dimethyl oxalate with phenol. All the samples were active for the transesterification. Among them, the sample AEP-MCM-41 exhibited the highest activity under test conditions. And only a slight decrease in activity could be observed after few runs, indicating the good recyclability of this catalyst. Notably, the activity of the used catalyst could be regenerated by simple treatment with diluted basic agents under mild conditions. Moreover, effects of the density and the basic strength of the amino groups on the catalytic properties were taken into consideration for understanding the reaction mechanism and the possible formation route of the by-product anisole.
关键词	Amino-functionalized Mcm-41 Dimethyl Oxalate Transesterification Recyclability
语种	英语
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/666
专题	生物基材料组群
推荐引用方式 GB/T 7714	Liu, Y ,Zhao, GM ,Zhu, WC ,et al. Comparative Study on the Catalytic Properties of Amino-Functionalized SilicaMaterials for the Transesterification of Dimethyl Oxalate With Phenol[J]. JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY,2010,21(12):2254-2261.
APA	Liu, Y .,Zhao, GM .,Zhu, WC .,Wang, J .,Liu, G .,...&Jia, MJ .(2010).Comparative Study on the Catalytic Properties of Amino-Functionalized SilicaMaterials for the Transesterification of Dimethyl Oxalate With Phenol.JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY,21(12),2254-2261.
MLA	Liu, Y ,et al."Comparative Study on the Catalytic Properties of Amino-Functionalized SilicaMaterials for the Transesterification of Dimethyl Oxalate With Phenol".JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY 21.12(2010):2254-2261.

条目包含的文件		下载所有文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
Comparative Study on（276KB）			开放获取	--	浏览 下载

个性服务

推荐该条目

保存到收藏夹

查看访问统计

导出为Endnote文件

谷歌学术

谷歌学术中相似的文章

[Liu, Y (Liu, Yan)1]的文章

[Zhao, GM (Zhao, Guoming)2]的文章

[Zhu, WC (Zhu, Wanchun)1]的文章

百度学术

百度学术中相似的文章

[Liu, Y (Liu, Yan)1]的文章

[Zhao, GM (Zhao, Guoming)2]的文章

[Zhu, WC (Zhu, Wanchun)1]的文章

必应学术

必应学术中相似的文章

[Liu, Y (Liu, Yan)1]的文章

[Zhao, GM (Zhao, Guoming)2]的文章

[Zhu, WC (Zhu, Wanchun)1]的文章

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。