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Effects of different anionic surfactants on methane hydrate formation
Wang, Fei1,2; Jia, Zhen-Zhen3; Luo, Sheng-Jun1; Fu, Shan-Fei1,2; Wang, Lin1; Shi, Xiao-Shuang1; Wang, Chuan-Shui1; Guo, Rong-Bo1
2015-12-01
发表期刊CHEMICAL ENGINEERING SCIENCE
卷号137页码:896-903
摘要In this work, the effects of anionic surfactants on methane hydrate formation were studied. For comparison, three anionic surfactants with the same carbon chain but different head groups, sodium dodecyl sulfonate (SDSN), sodium dodecyl sulfate (SDS) and sodium dodecyl benzene sulfonate (SDBS) were used. SOBS was detected to form micelles under hydrate formation conditions, while SDSN and SDS precipitated before micelles were formed. As a result, concentrations of SDSN and SOS did not show obvious influence on the promotion effect to methane hydrate formation, while the concentration of SOBS significantly affected the promotion effect because of the micelle effect. When SDSN and SDS were used hydrates grew upwards on the reactor wall due to the relatively narrow contact angle of the surfactant solutions on the reactor sidewall, while SDBS led to the hydrates formed mainly in the bottom of the reactor as a result of the relatively wide contact angle. In addition, SDSN and SDS led to much higher growth rate in comparison to SOBS due to the upward growth of hydrates on the reactor sidewall. (C) 2015 Elsevier Ltd. All rights reserved.
文章类型Article
关键词Methane Hydrates Anionic Surfactants Induction Time Contact Angle Hydrate Growth
WOS标题词Science & Technology ; Technology
DOI10.1016/j.ces.2015.07.021
关键词[WOS]SODIUM DODECYL-SULFATE ; UNSTIRRED GAS/LIQUID SYSTEM ; GAS HYDRATE ; AMBIENT-TEMPERATURE ; FORMING CONDITIONS ; FORMATION KINETICS ; AQUEOUS-SOLUTION ; ALKYL SULFATES ; STORAGE ; SOLUBILITY
收录类别SCI
语种英语
WOS研究方向Engineering
WOS类目Engineering, Chemical
WOS记录号WOS:000361772400082
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/6602
专题工业生物燃气研究组
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Shandong Ind Engn Lab Biogas Prod & Utilizat, Qingdao 266101, Shandong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Guizhou Univ, Guiyang 550025, Peoples R China
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Wang, Fei,Jia, Zhen-Zhen,Luo, Sheng-Jun,et al. Effects of different anionic surfactants on methane hydrate formation[J]. CHEMICAL ENGINEERING SCIENCE,2015,137:896-903.
APA Wang, Fei.,Jia, Zhen-Zhen.,Luo, Sheng-Jun.,Fu, Shan-Fei.,Wang, Lin.,...&Guo, Rong-Bo.(2015).Effects of different anionic surfactants on methane hydrate formation.CHEMICAL ENGINEERING SCIENCE,137,896-903.
MLA Wang, Fei,et al."Effects of different anionic surfactants on methane hydrate formation".CHEMICAL ENGINEERING SCIENCE 137(2015):896-903.
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