Synthesis, crystal structure and anticancer activity of 2D-coordination polymer of cerium(III) with chiral Schiff base trans-N,N '-bis-(2-hydroxy-1-naphthalidehydene)-(1R,2R)-cyclohexanediamine | |
Fan, Yu-Hua1; Wang, Ai-Dong1,2; Bi, Cai-Feng1; Xiao, Yan1,3; Bi, Shuang-Yu1; Zhang, Xia1; Wang, Qiang1 | |
2011-08-01 | |
发表期刊 | SYNTHETIC METALS |
卷号 | 161期号:15-16页码:1552-1556 |
摘要 | The chiral Schiff base coordination polymer [Ce(H2L)(3)(NO3)(3)Ce(H2L)(3)(NO3)(3)(H2O)](n) [H2L: trans-N,N'-bis(2-hydroxy-1-naphthalidehy-dene)-(1R,2R)-cyclohexanediamine] was synthesized and characterized by infrared spectroscopy, elemental analysis and single-crystal X-ray diffraction analysis. X-ray crystallography shows that the Ce(III) coordinates with three neutral Schiff base ligands and three nitrates. One Ce(III) is nine-coordinated by three oxygen atoms from three different Schiff base ligands and six oxygen atoms from three nitrates, the other Ce(III) is ten-coordinated because of the coordination of an additional water molecule. Each Schiff base ligand serves as a bridging ligand to link Ce(III) ions through oxygen atoms, leading to a coordination polymer. The Ce(III) coordination polymer displays two dimensional plane grid network structure. The antiproliferation activities of the ligand H2L and its Ce(III) coordination polymer on MDA-MB-231 breast cancer cells were also studied by MTT(3-[4,5-dimethyltiazol-2-yl]-2,5-diphenyltetrazolium bromide) method. The results indicate that H2L and [Ce(H2L)(3)(NO3)(3)Ce(H2L)(3)(NO3)(3)(H2O)](n) can inhibit the cellularproliferation. Moreover, the coordination polymer had higher antiproliferative activity than that of the ligand. (C) 2011 Elsevier B.V. All rights reserved. |
文章类型 | Article |
关键词 | Chiral Schiff Base Cerium(Iii) Coordination Polymer Crystal Structure Antiproliferation |
WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
DOI | 10.1016/j.synthmet.2011.05.014 |
关键词[WOS] | PROTEASOME INHIBITORS ; ZINC(II) COMPLEXES ; COPPER COMPLEX ; CANCER ; APOPTOSIS ; LIGAND |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Materials Science ; Physics ; Polymer Science |
WOS类目 | Materials Science, Multidisciplinary ; Physics, Condensed Matter ; Polymer Science |
WOS记录号 | WOS:000294971700016 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6553 |
专题 | 代谢物组学研究组 |
作者单位 | 1.Ocean Univ China, Coll Chem & Chem Engn, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Shandong, Peoples R China 2.Coll Huangshan, Dept Chem, Huangshan 245041, Peoples R China 3.Chinese Acad Sci, Key Lab Biofuels, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266100, Shandong, Peoples R China |
推荐引用方式 GB/T 7714 | Fan, Yu-Hua,Wang, Ai-Dong,Bi, Cai-Feng,et al. Synthesis, crystal structure and anticancer activity of 2D-coordination polymer of cerium(III) with chiral Schiff base trans-N,N '-bis-(2-hydroxy-1-naphthalidehydene)-(1R,2R)-cyclohexanediamine[J]. SYNTHETIC METALS,2011,161(15-16):1552-1556. |
APA | Fan, Yu-Hua.,Wang, Ai-Dong.,Bi, Cai-Feng.,Xiao, Yan.,Bi, Shuang-Yu.,...&Wang, Qiang.(2011).Synthesis, crystal structure and anticancer activity of 2D-coordination polymer of cerium(III) with chiral Schiff base trans-N,N '-bis-(2-hydroxy-1-naphthalidehydene)-(1R,2R)-cyclohexanediamine.SYNTHETIC METALS,161(15-16),1552-1556. |
MLA | Fan, Yu-Hua,et al."Synthesis, crystal structure and anticancer activity of 2D-coordination polymer of cerium(III) with chiral Schiff base trans-N,N '-bis-(2-hydroxy-1-naphthalidehydene)-(1R,2R)-cyclohexanediamine".SYNTHETIC METALS 161.15-16(2011):1552-1556. |
条目包含的文件 | 下载所有文件 | |||||
文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
Synthesis, crystal s(739KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论