Improved Cycle Stability and Rate Capability of Graphene Oxide Wrapped Tavorite LiFeSO4F as Cathode Material for Lithium-Ion Batteries

doi:10.1021/acsami.5b02966

QIBEBT-IR > 代谢物组学研究组

	Improved Cycle Stability and Rate Capability of Graphene Oxide Wrapped Tavorite LiFeSO4F as Cathode Material for Lithium-Ion Batteries
	Guo, Zhendong 1; Zhang, Dong 1; Qiu, Hailong 1; Zhang, Tong 1; Fu, Qiang 1; Zhang, Lijie 1; Yan, Xiao3 ; Meng, Xing 1; Chen, Gang 1,2; Wei, Yingjin 1
	2015-07-01
发表期刊	ACS APPLIED MATERIALS & INTERFACES
卷号	7 期号:25 页码:13972-13979
摘要	Tavorite LiFeSO4F has been regarded as a promising alternative to LiFePO4 due to its high Li ionic conductivity. To overcome the low electronic conductivity of LiFeSO4F, we prepared a graphene oxide (GO)/LiFeSO4F composite material by the solvothermal method. The GO wraps on the surface of LiFeSO4F and links the adjacent particles, thus providing an effective network for electrons transport. As a result, the electronic conductivity of the material is improved from 8.16 x 10(-11) S cm(-1) to 1.65 x 10(-4) S cm(-1). In addition, the GO depresses the side reactions of the electrode and electrolyte, promotes the charge transfer reactions at the electrode/electrolyte interface, and facilitates the lithium diffusion in the electrode. The GO-wrapped LiFeSO4F exhibits much better electrochemical performance than the pristine material. It showed a discharge capacity of 113.2 mAh g(-1) at the 0.1 C rate with 99% capacity retention after 100 cycles. In addition, the material is able to deliver 85.1, 73.4, and 30.3 mAh g-1 at high current rates of 1 C, 2 C, and 10 C, respectively.
文章类型	Article
关键词	Lithium Ion Batteries Cathode Material Lithium Iron Sulfate Fluoride Graphene Oxide Electrochemical Performance
WOS标题词	Science & Technology ; Technology
DOI	10.1021/acsami.5b02966
关键词[WOS]	POSITIVE ELECTRODE INTERFACE ; ELECTROCHEMICAL PERFORMANCE ; SULFUR BATTERIES ; ANODE MATERIAL ; LINI0.5MN1.5O4 ; INTERCALATION ; FRAMEWORK ; CAPACITY ; STORAGE ; SURFACE
收录类别	SCI
语种	英语
WOS研究方向	Science & Technology - Other Topics ; Materials Science
WOS类目	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000357436800029
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6513
专题	代谢物组学研究组
作者单位	1.Jilin Univ, Coll Phys, Key Lab Phys & Technol Adv Batteries, Minist Educ, Changchun 130012, Peoples R China 2.Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Peoples R China 3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Guo, Zhendong,Zhang, Dong,Qiu, Hailong,et al. Improved Cycle Stability and Rate Capability of Graphene Oxide Wrapped Tavorite LiFeSO4F as Cathode Material for Lithium-Ion Batteries[J]. ACS APPLIED MATERIALS & INTERFACES,2015,7(25):13972-13979.
APA	Guo, Zhendong.,Zhang, Dong.,Qiu, Hailong.,Zhang, Tong.,Fu, Qiang.,...&Wei, Yingjin.(2015).Improved Cycle Stability and Rate Capability of Graphene Oxide Wrapped Tavorite LiFeSO4F as Cathode Material for Lithium-Ion Batteries.ACS APPLIED MATERIALS & INTERFACES,7(25),13972-13979.
MLA	Guo, Zhendong,et al."Improved Cycle Stability and Rate Capability of Graphene Oxide Wrapped Tavorite LiFeSO4F as Cathode Material for Lithium-Ion Batteries".ACS APPLIED MATERIALS & INTERFACES 7.25(2015):13972-13979.