Methylamine-Gas-Induced Defect-Healing Behavior of CH3NH3PbI3 Thin Films for Perovskite Solar Cells

doi:10.1002/anie.201504379

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	Methylamine-Gas-Induced Defect-Healing Behavior of CH3NH3PbI3 Thin Films for Perovskite Solar Cells
	Zhou, Zhongmin 1; Wang, Zaiwei 1; Zhou, Yuanyuan 2; Pang, Shuping 1; Wang, Dong 1; Xu, Hongxia 1; Liu, Zhihong 1; Padture, Nitin P.2; Cui, Guanglei1
	2015-08-10
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷号	54 期号:33 页码:9705-9709
摘要	We report herein the discovery of methylamine (CH3NH2) induced defect-healing (MIDH) of CH3NH3PbI3 perovskite thin films based on their ultrafast (seconds), reversible chemical reaction with CH3NH2 gas at room temperature. The key to this healing behavior is the formation and spreading of an intermediate CH(3)NH(3)PbI(3)xCH(3)NH(2) liquid phase during this unusual perovskite-gas interaction. We demonstrate the versatility and scalability of the MIDH process, and show dramatic enhancement in the performance of perovskite solar cells (PSCs) with MIDH. This study represents a new direction in the formation of defect-free films of hybrid perovskites.
文章类型	Article
关键词	Defect Healing Methylamine Perovskite Phases Photovoltaics Thin Film
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1002/anie.201504379
关键词[WOS]	ORGANOMETAL HALIDE PEROVSKITES ; CRYSTALLIZATION ; DEPOSITION ; EMERGENCE
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000358987300050
引用统计	被引频次：168[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6506
专题	仿生能源与储能系统团队
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Brown Univ, Sch Engn, Providence, RI 02912 USA
推荐引用方式 GB/T 7714	Zhou, Zhongmin,Wang, Zaiwei,Zhou, Yuanyuan,et al. Methylamine-Gas-Induced Defect-Healing Behavior of CH3NH3PbI3 Thin Films for Perovskite Solar Cells[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2015,54(33):9705-9709.
APA	Zhou, Zhongmin.,Wang, Zaiwei.,Zhou, Yuanyuan.,Pang, Shuping.,Wang, Dong.,...&Cui, Guanglei.(2015).Methylamine-Gas-Induced Defect-Healing Behavior of CH3NH3PbI3 Thin Films for Perovskite Solar Cells.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,54(33),9705-9709.
MLA	Zhou, Zhongmin,et al."Methylamine-Gas-Induced Defect-Healing Behavior of CH3NH3PbI3 Thin Films for Perovskite Solar Cells".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54.33(2015):9705-9709.