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Sorbitol hydrogenolysis to glycerol and glycols over M-MgO (M = Ni, Co, Cu) nanocomposite: A comparative study of active metals
Wang, Xicheng1; Liu, Xiaoran1,2; Xu, Yue3; Peng, Gongming1; Cao, Quan1; Mu, Xindong1
2015-09-01
发表期刊CHINESE JOURNAL OF CATALYSIS
卷号36期号:9页码:1614-1622
摘要The activities and selectivities of MgO-supported Ni, Cu, and Co catalysts have been compared in aqueous-phase hydrogenolysis of sorbitol to glycerol and glycols. All catalysts effectively catalyzed the sorbitol conversion into C2 and C3 polyols like glycerol, 1,2-propylene glycol, and ethylene glycol, but with different product distributions. The differences in activities and selectivities are ascribed to their different dehydrogenation/hydrogenation activities. The influences of base promoter, temperature, H-2 pressure, and reaction time were also studied. Added base promoter and prolonged reaction time enhanced sorbitol conversion for the three catalysts, but led to product degradation and decreased selectivity over Ni-MgO and Co-MgO, whereas selectivity maintained almost unchanged over Cu-MgO. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
文章类型Article
关键词Biomass Hydrogenolysis Sorbitol Magnesia Supported Metal Catalyst Bifunctional Catalyst
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/S1872-2067(15)60928-7
关键词[WOS]SUPPORTED RUTHENIUM CATALYST ; BIODIESEL DERIVED GLYCEROL ; ETHYLENE-GLYCOL ; CELLULOSE ; 1,2-PROPANEDIOL ; CONVERSION ; CHEMICALS ; BIOMASS ; 1,2-ALKANEDIOLS
收录类别SCI
语种英语
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS记录号WOS:000361084300023
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文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/6490
专题绿色化学催化团队
作者单位1.Chinese Acad Sci, Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
2.Univ Chinese Acad Sci, Being 100049, Peoples R China
3.China Univ Geosci, Sch Water Resources & Environm, Beijing 100083, Peoples R China
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Wang, Xicheng,Liu, Xiaoran,Xu, Yue,et al. Sorbitol hydrogenolysis to glycerol and glycols over M-MgO (M = Ni, Co, Cu) nanocomposite: A comparative study of active metals[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(9):1614-1622.
APA Wang, Xicheng,Liu, Xiaoran,Xu, Yue,Peng, Gongming,Cao, Quan,&Mu, Xindong.(2015).Sorbitol hydrogenolysis to glycerol and glycols over M-MgO (M = Ni, Co, Cu) nanocomposite: A comparative study of active metals.CHINESE JOURNAL OF CATALYSIS,36(9),1614-1622.
MLA Wang, Xicheng,et al."Sorbitol hydrogenolysis to glycerol and glycols over M-MgO (M = Ni, Co, Cu) nanocomposite: A comparative study of active metals".CHINESE JOURNAL OF CATALYSIS 36.9(2015):1614-1622.
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