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Title:
Functional lithium borate salts and their potential application in high performance lithium batteries
Author: Liu, Zhihong1; Chai, Jingchao1,2; Xu, Gaojie1; Wang, Qingfu1; Cui GuangLei(崔光磊)1
Source: COORDINATION CHEMISTRY REVIEWS
Issued Date: 2015-05-15
Volume: 292, Issue:1, Pages:56-73
Keyword: Review ; Lithium borate salts ; Lithium ion battery ; Polymeric electrolyte ; Single-ion conductor
DOI: 10.1016/j.ccr.2015.02.011
DOC Type: Review
English Abstract:

Lithium borate salts have been arousing intensive interest due to their unique properties such as excellent thermal stability, comparable ionic conductivity, cost-effectiveness, environmental benignity and favorable solid electrolyte interface forming property. Herein, the recent progress of many lithium borate salts and their potential application in high performance lithium batteries using the Si/C composite anode, lithium metal anode, high voltage cathodes or semi-solid lithium flowable electrodes are reviewed in regard to their synthesis, properties and battery performance. This review also presents the current progress of single-ion conducting polymeric lithium borate salts, which exhibit high lithium ion transference numbers approaching unit. These single-ion dominantly conducting polymeric electrolytes are very desirable in lithium batteries with less polarization since the electrodes only exchange lithium ions with electrolytes. We hope that the new and established researchers in the battery area can obtain a clear perspective of this field and our review can provide the motivation for new attempts in this promising field. (C) 2015 Elsevier B.V. All rights reserved.

WOS Headings: Science & Technology ; Physical Sciences
WOS Subject: Chemistry, Inorganic & Nuclear
WOS Subject Extended: Chemistry
WOS Keyword Plus: LI-ION BATTERIES ; LIBOB-BASED ELECTROLYTES ; POLYANIONIC SOLID ELECTROLYTES ; VOLTAGE SPINEL LINI0.5MN1.5O4 ; GEL POLYMER ELECTROLYTES ; WEAK COULOMB TRAPS ; RECHARGEABLE LITHIUM ; PROPYLENE CARBONATE ; ELECTROCHEMICAL PERFORMANCE ; GAMMA-BUTYROLACTONE
Indexed Type: SCI
Language: 英语
WOS ID: WOS:000354585400004
Citation statistics:
Content Type: 期刊论文
URI: http://ir.qibebt.ac.cn/handle/337004/6486
Appears in Collections:仿生能源与储能系统团队_期刊论文

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description.institution: 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Liu, Zhihong,Chai, Jingchao,Xu, Gaojie,et al. Functional lithium borate salts and their potential application in high performance lithium batteries[J]. COORDINATION CHEMISTRY REVIEWS,2015,292(1):56-73.
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