Design of mesoporous KA zeolite supported sulfur-tolerant noble metal catalyst for naphthalene hydrogenation

doi:10.1016/j.fuel.2015.03.035

QIBEBT-IR > 热化学转化研究组

	Design of mesoporous KA zeolite supported sulfur-tolerant noble metal catalyst for naphthalene hydrogenation
	Ju, Chao 1; Wang, Yuxin 2; Huang, Yong 1; Fang, Yunming 1
	2015-08-15
发表期刊	FUEL
卷号	154 页码:80-87
摘要	As the demand for the high-quality transportation fuels grow rapidly, deep hydrogenation of diesel for aromatics reduction plays an important role in petroleum refinery. In this paper, a sulfur-tolerant noble metal hydrogenation catalyst, Pt/mesoporous KA zeolite (Pt/MKAZ), was developed based on the shape selective and hydrogen spillover concepts. Different kinds of catalysts were prepared by carefully adjusting the contents of Pt in the cages of MKAZ and its additional mesopore channels, and their performances were tested in naphthalene hydrogenation with either 3 mol% of H2S in hydrogen or 3000 ppm of dibenzothiophene (DBT) in naphthalene feedstock. The results indicated that the distributions of Pt in both cages and mesopore channels of MKAZ could be controlled well and the resultant catalyst with an optimized nanostructure showed an excellent sulfur resistance in naphthalene hydrogenation due to a synergetic effect of Pt confined in the cages and mesopore channels. (C) 2015 Elsevier Ltd. All rights reserved.
文章类型	Article
关键词	Mesoporous Zeolite Platinum Sulfur Tolerant Shape Selective Hydrogen Spillover
WOS标题词	Science & Technology ; Technology
DOI	10.1016/j.fuel.2015.03.035
关键词[WOS]	DEEP DESULFURIZATION ; CRYSTALLINE ZEOLITE ; SINGLE-CRYSTALS ; 4,6-DIMETHYLDIBENZOTHIOPHENE ; HYDRODESULFURIZATION ; SELECTIVITY ; AROMATICS ; SPILLOVER ; PALLADIUM
收录类别	SCI
语种	英语
WOS研究方向	Energy & Fuels ; Engineering
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000353893200010
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6447
专题	热化学转化研究组
作者单位	1.Beijing Univ Chem Technol, Dept Chem Engn, State Key Lab Organ Inorgan Composite, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Ju, Chao,Wang, Yuxin,Huang, Yong,et al. Design of mesoporous KA zeolite supported sulfur-tolerant noble metal catalyst for naphthalene hydrogenation[J]. FUEL,2015,154:80-87.
APA	Ju, Chao,Wang, Yuxin,Huang, Yong,&Fang, Yunming.(2015).Design of mesoporous KA zeolite supported sulfur-tolerant noble metal catalyst for naphthalene hydrogenation.FUEL,154,80-87.
MLA	Ju, Chao,et al."Design of mesoporous KA zeolite supported sulfur-tolerant noble metal catalyst for naphthalene hydrogenation".FUEL 154(2015):80-87.