Heat-resistant and rigid-flexible coupling glass-fiber nonwoven supported polymer electrolyte for high-performance lithium ion batteries | |
Wang, Qingfu1,2; Zhang, Bo1; Zhang, Jianjun1; Yu, Yong2; Hu, Pu1; Zhang, Chuanjian1; Ding, Guoliang1; Liu, Zhihong1; Zong, Chengzhong2; Cui, Guanglei1 | |
2015-03-01 | |
发表期刊 | ELECTROCHIMICA ACTA |
卷号 | 157页码:191-198 |
摘要 | A heat-resistant and rigid-flexible coupling glass-microfiber nonwoven supported cyanoethyl-beta-polyvinyl alcohol composite polymer electrolyte membrane (GFMPE) has been successfully fabricated explored for high-performance lithium batteries. It was demonstrated that the GFMPE possessed enhanced mechanical property, superior dimensional thermostability (>200 degrees C). In addition, Ethylene carbonate (EC)/Dimethyl carbonate (DMC) solvent soaked GFMPE exhibited a superior Li ion transport number of 0.86, wide electrochemical window up to 4.8V vs Li+/Li and high ionic conductivity of 0.89 mS/cm at 25 degrees C. Moreover, LiCoO2/graphite cells using such polymer electrolyte with EC: DMC (1: 1, v/v) showed excellent cycling stability and superior rate capability at room temperature. It is important to note that the LiFePO4/Li cell using GFMPE/propylene carbonate (PC) can also operate very well at an elevated temperature of 120 degrees C. These fascinating results would endow GFMPE a very promising polymer electrolyte in high-performance lithium batteries with improved safety and reliablity. (C) 2015 Elsevier Ltd. All rights reserved. |
文章类型 | Article |
关键词 | Cyanoethyl-beta-polyvinylalcohol Fiber-glass Nonwoven Gel Composite Polymer Electrolyte Lithium Batteries |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1016/j.electacta.2015.01.083 |
关键词[WOS] | ELECTRICAL ENERGY-STORAGE ; ELECTROCHEMICAL PROPERTIES ; SEPARATOR ; BLENDS ; CONDUCTION ; MEMBRANES ; NETWORK ; PAPER |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Electrochemistry |
WOS类目 | Electrochemistry |
WOS记录号 | WOS:000350445500025 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6401 |
专题 | 仿生与固态能源系统研究组 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Qingdao Univ Sci & Technol, Qingdao 266042, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Qingfu,Zhang, Bo,Zhang, Jianjun,et al. Heat-resistant and rigid-flexible coupling glass-fiber nonwoven supported polymer electrolyte for high-performance lithium ion batteries[J]. ELECTROCHIMICA ACTA,2015,157:191-198. |
APA | Wang, Qingfu.,Zhang, Bo.,Zhang, Jianjun.,Yu, Yong.,Hu, Pu.,...&Cui, Guanglei.(2015).Heat-resistant and rigid-flexible coupling glass-fiber nonwoven supported polymer electrolyte for high-performance lithium ion batteries.ELECTROCHIMICA ACTA,157,191-198. |
MLA | Wang, Qingfu,et al."Heat-resistant and rigid-flexible coupling glass-fiber nonwoven supported polymer electrolyte for high-performance lithium ion batteries".ELECTROCHIMICA ACTA 157(2015):191-198. |
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