| Benzodithiophene-Based Poly(aryleneethynylene)s: Synthesis, Optical Properties, and Applications in Organic Solar Cells | |
| Wen, Shuguang1; Bao, Xichang1; Shen, Wenfei1,2; Gu, Chuantao1; Du, Zhengkun1; Han, Liangliang1; Zhu, Dangqiang1; Yang, Renqiang1 | |
| 2014-02-15 | |
| 发表期刊 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
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| 卷号 | 52期号:2页码:208-215 |
| 摘要 | The synthesis and characterization of building block of ethynylene-substituted benzo[1,2-b:4,5-b]dithiophene (BDT), and its application in the construction of poly(aryleneethynylene)s (PAEs) are described in this article. Alkoxy-substituted BDT and thiazolothiazole are selected as the other copolymerized units, and polymers of PEBBDT and PEBTTZ were synthesized by Pd-catalyzed Sonogashira coupling reaction. These polymers showed intense interchain - interaction and deep HOMO levels ( -5.50 eV). Bulk heterojunction solar cell fabricated using PEBBDT or PEBTTZ as electron donor and PC61BM as acceptor display power conversion efficiency of 0.85 and 2.40%, respectively, under the illumination of AM1.5G, 100 mW cm(-2). This study shows good prospect for the application of PAEs-type polymers in organic solar cell. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 208-215 |
| 文章类型 | Article |
| 关键词 | Bulk-heterojunction Charge Transfer Conjugated Polymer Heteroatom-containing Polymers Organic Solar Cell Poly(Aryleneethynylene)s Structure Property Relationships |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1002/pola.26989 |
| 关键词[WOS] | OPEN-CIRCUIT VOLTAGE ; PHOTOVOLTAIC PROPERTIES ; SIDE-CHAINS ; POLYMER ; DONOR ; MORPHOLOGY ; EFFICIENCY ; COPOLYMER ; DESIGN |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| WOS记录号 | WOS:000328051600007 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6381 |
| 专题 | 先进有机功能材料研究组 |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Qingdao Univ, Inst Hybrid Mat, Lab New Fiber Mat & Modern Text, Growing Base State Key Lab, Qingdao 266071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wen, Shuguang,Bao, Xichang,Shen, Wenfei,et al. Benzodithiophene-Based Poly(aryleneethynylene)s: Synthesis, Optical Properties, and Applications in Organic Solar Cells[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2014,52(2):208-215. |
| APA | Wen, Shuguang.,Bao, Xichang.,Shen, Wenfei.,Gu, Chuantao.,Du, Zhengkun.,...&Yang, Renqiang.(2014).Benzodithiophene-Based Poly(aryleneethynylene)s: Synthesis, Optical Properties, and Applications in Organic Solar Cells.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,52(2),208-215. |
| MLA | Wen, Shuguang,et al."Benzodithiophene-Based Poly(aryleneethynylene)s: Synthesis, Optical Properties, and Applications in Organic Solar Cells".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 52.2(2014):208-215. |
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| Benzodithiophene-Bas（377KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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