| Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer | |
| Peng, Gongming; Wang, Xicheng; Chen, Xiufang; Jiang, Yijun; Mu, Xindong | |
| 2014-09-25 | |
| 发表期刊 | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
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| 卷号 | 20期号:5页码:2641-2645 |
| 摘要 | Vapor-phase catalytic dehydration of 1,2-propanediol was investigated over Zirconia-supported niobia catalysts. The catalysts exhibit selectivity favoring propanol (approximately 39%) at 85.0% 1,2-propanediol conversion at 290 degrees C under 1 atm N-2. The ZrNbO catalysts were analyzed by various techniques; the results indicated that the active sites were weak Bronsted acid sites. A dehydration and hydrogen transfer mechanism was also proposed. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved. |
| 文章类型 | Article |
| 关键词 | Zirconia-supported Niobia Hydrogen Transfer 1 2-propanediol |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1016/j.jiec.2013.11.042 |
| 关键词[WOS] | GLYCEROL HYDROGENOLYSIS ; SELECTIVE OXIDATION ; BASE ; DIHYDROXYACETONE ; BIOPROPANOLS ; ACROLEIN ; ACIDITY ; REOX |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Multidisciplinary ; Engineering, Chemical |
| WOS记录号 | WOS:000339692100004 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6362 |
| 专题 | 绿色化学催化研究组 |
| 作者单位 | Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, Gongming,Wang, Xicheng,Chen, Xiufang,et al. Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,2014,20(5):2641-2645. |
| APA | Peng, Gongming,Wang, Xicheng,Chen, Xiufang,Jiang, Yijun,&Mu, Xindong.(2014).Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer.JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,20(5),2641-2645. |
| MLA | Peng, Gongming,et al."Zirconia-supported niobia catalyzed formation of propanol from 1,2-propanediol via dehydration and consecutive hydrogen transfer".JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 20.5(2014):2641-2645. |
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| Zirconia-supported n（606KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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