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Aligned nanoporous PtNi nanorod-like structures for electrocatalysis and biosensing (Retracted article. See vol. 2, pg. 13042, 2012)
Qiu, Huajun1,3; Li, Liang2; Lang, Qiaolin2; Zou, Feixue1; Huang, Xirong1
2012
发表期刊RSC ADVANCES
卷号2期号:8页码:3548-3554
摘要We describe the one-step dealloying of PtNiAl ternary alloy to fabricate aligned nanoporous PtNi (np-PtNi) nanorod-like structures with predetermined alloy composition. Electron microscopy and X-ray diffraction characterizations demonstrate that the selective etching of Al from PtNiAl alloy with multiphases generates aligned np-PtNi alloy nanorods. The formation of nanoporous nanorod-like structures with uniform PtNi alloy ligament should be due to the fast diffusion, self assembly and strong interaction between Pt and Ni during the dealloying process. With the ligament size less than 5 nm, the np-PtNi nanorods exhibit remarkably improved electrocatalytic activity towards ethanol oxidation and H2O2 oxidation/reduction compared with the commercial Pt/C catalyst. When coupled with glucose oxidase, the enzyme modified np-PtNi electrode can sensitively detect glucose over a wide linear range (0.5-21 mM).
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c2ra01308h
关键词[WOS]OXYGEN REDUCTION REACTION ; METHANOL ELECTROOXIDATION ; CARBON NANOTUBES ; HORSERADISH-PEROXIDASE ; GOLD NANOWIRES ; POROUS GOLD ; SOL-GEL ; ALLOY ; CATALYSTS ; SURFACE
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000302023500066
引用统计
被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/6343
专题生物传感技术团队(过去)
作者单位1.Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
3.Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637457, Singapore
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Qiu, Huajun,Li, Liang,Lang, Qiaolin,et al. Aligned nanoporous PtNi nanorod-like structures for electrocatalysis and biosensing (Retracted article. See vol. 2, pg. 13042, 2012)[J]. RSC ADVANCES,2012,2(8):3548-3554.
APA Qiu, Huajun,Li, Liang,Lang, Qiaolin,Zou, Feixue,&Huang, Xirong.(2012).Aligned nanoporous PtNi nanorod-like structures for electrocatalysis and biosensing (Retracted article. See vol. 2, pg. 13042, 2012).RSC ADVANCES,2(8),3548-3554.
MLA Qiu, Huajun,et al."Aligned nanoporous PtNi nanorod-like structures for electrocatalysis and biosensing (Retracted article. See vol. 2, pg. 13042, 2012)".RSC ADVANCES 2.8(2012):3548-3554.
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