Ni-Cu/ZnO-catalyzed Hydrogenolysis of Cellulose for the Production of 1,2-Alkanediols in Hot Compressed Water | |
Wang, Xicheng1,2; Wu, Feng1,3; Yao, Shengxi1; Jiang, Yijun1; Guan, Jing1; Mui, Xindong1 | |
2012-05-05 | |
发表期刊 | CHEMISTRY LETTERS |
卷号 | 41期号:5页码:476-478 |
摘要 | Ni-Cu/ZnO catalysts with varied Ni-to-Cu mole ratio were prepared by coprecipitation and evaluated for the hydrogenolysis of high-crystalline cellulose. Ni and Cu species exerted synergetic effects in dehydroxylation reaction and C-C bond breakage for the formation of 1,2-alkanediols. Ni-Cu/ZnO with Ni-to-Cu ratio of 2:3 is highly selective toward 1,2-alkanediols (72.5%) under hydrothermal conditions (518 K, 4 MPa H-2), which also exhibits excellent activity in the conversion of real biomass. |
文章类型 | Article |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1246/cl.2012.476 |
关键词[WOS] | ETHYLENE-GLYCOL ; CONVERSION ; CHEMICALS ; GLYCEROL ; POLYOLS |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
WOS记录号 | WOS:000304517600002 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6341 |
专题 | 绿色化学催化研究组 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China 2.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266061, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Xicheng,Wu, Feng,Yao, Shengxi,et al. Ni-Cu/ZnO-catalyzed Hydrogenolysis of Cellulose for the Production of 1,2-Alkanediols in Hot Compressed Water[J]. CHEMISTRY LETTERS,2012,41(5):476-478. |
APA | Wang, Xicheng,Wu, Feng,Yao, Shengxi,Jiang, Yijun,Guan, Jing,&Mui, Xindong.(2012).Ni-Cu/ZnO-catalyzed Hydrogenolysis of Cellulose for the Production of 1,2-Alkanediols in Hot Compressed Water.CHEMISTRY LETTERS,41(5),476-478. |
MLA | Wang, Xicheng,et al."Ni-Cu/ZnO-catalyzed Hydrogenolysis of Cellulose for the Production of 1,2-Alkanediols in Hot Compressed Water".CHEMISTRY LETTERS 41.5(2012):476-478. |
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