| Direct alpha-Alkylation of Ketones with Alcohols in Water | |
Xu, Guoqiang1 ; Li, Qiong1,2; Feng, Jiange2; Liu, Qiang1; Zhang, Zuojun1; Wang, Xicheng1; Zhang, Xiaoyun2; Mu, Xindong1
| |
| 2014 | |
| 发表期刊 | CHEMSUSCHEM
 |
| 卷号 | 7期号:1页码:105-109 |
| 摘要 | The direct alpha-alkylation of ketones with alcohols has emerged as a new green protocol to construct C-C bonds with H2O as the sole byproduct. In this work, a very simple and convenient Pd/C catalytic system for the direct alpha-alkylation of ketones with primary alcohols in pure water is developed. Based on this catalytic system, aqueous mixtures of dilute acetone, 1-butanol, and ethanol (mimicking ABE fermentation products) can be directly transformed into C-5-C-11 or longer-chain ketones and alcohols, which are precursors to fuels. |
| 文章类型 | Article |
| 关键词 | Alcohols Alkylations Aqueous-phase Reforming Heterogeneous Catalysis Ketones |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1002/cssc.201300815 |
| 关键词[WOS] | CATALYZED ALKYLATION ; TRANSFORMATIONS ; SOLVENT ; FUELS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| WOS记录号 | WOS:000336802400012 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6327 |
| 专题 | 绿色化学催化研究组 |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.China Univ Petr, Coll Sci, Qingdao 266555, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Guoqiang,Li, Qiong,Feng, Jiange,et al. Direct alpha-Alkylation of Ketones with Alcohols in Water[J]. CHEMSUSCHEM,2014,7(1):105-109. |
| APA | Xu, Guoqiang.,Li, Qiong.,Feng, Jiange.,Liu, Qiang.,Zhang, Zuojun.,...&Mu, Xindong.(2014).Direct alpha-Alkylation of Ketones with Alcohols in Water.CHEMSUSCHEM,7(1),105-109. |
| MLA | Xu, Guoqiang,et al."Direct alpha-Alkylation of Ketones with Alcohols in Water".CHEMSUSCHEM 7.1(2014):105-109. |
| 条目包含的文件 | 条目无相关文件。 | |||||
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