One-Step Conversion of Biomass-Derived 5-Hydroxymethylfurfural to 1,2,6-Hexanetriol Over Ni-Co-Al Mixed Oxide Catalysts Under Mild Conditions

doi:10.1021/sc4003714

QIBEBT-IR > 绿色化学催化研究组

	One-Step Conversion of Biomass-Derived 5-Hydroxymethylfurfural to 1,2,6-Hexanetriol Over Ni-Co-Al Mixed Oxide Catalysts Under Mild Conditions
	Yao, Shengxi 1; Wang, Xicheng 1; Jiang, Yijun 1; Wu, Feng 1; Chen, Xinguo 1; Mu, Xindong 1,2
	2014-02-01
发表期刊	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷号	2 期号:2 页码:173-180
摘要	The conversion of biomass-derived 5-hydroxymethylfurfural (HMF) was examined over Ni Co Al mixed oxide catalysts derived from corresponding hydrotalcite-like compounds (HTlcs). 1,2,6-Hexanetriol (1,2,6-HT) was obtained in 64.5% yield under mild reaction conditions. The catalysts were characterized by X-ray. powder diffraction (XRD), CO2 temperature-programthed desorption (CO2 TPD), N2 physical adsorption, and H2 temperatureprogrammed reduction (H2 TPR), and the reaction product distribution was correlated with the catalyst composition and reaction conditions. The reaction pathway was proposed based on the results. In all cases, the conversion of HMF proceeds according to a pathway that begins with the aldehyde group being hydrogenated to form 2,5-dihydroxymethylfuran (2,5-DHF). This product then undergoes a ring-opening reaction to form 1,2,6-HT. A synergetic effect between Ni and Co was observed, which significantly promoted catalytic activity and selectivity.
文章类型	Article
关键词	5-hydroxymethylfurfural Mixed Metal Oxide Catalyst 1 Nio 2 Coo 6-hexanetriol Furan Derivatives
WOS标题词	Science & Technology ; Physical Sciences ; Technology
DOI	10.1021/sc4003714
关键词[WOS]	CYCLIC ETHERS ; HYDROGENOLYSIS ; HYDROTALCITE ; MECHANISM ; ALCOHOL ; NOX ; CU
收录类别	SCI
语种	英语
WOS研究方向	Chemistry ; Engineering
WOS类目	Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号	WOS:000330812400009
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6319
专题	绿色化学催化研究组
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Qingdao Engn Res Ctr Biomass Green Chem Convers, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Yao, Shengxi,Wang, Xicheng,Jiang, Yijun,et al. One-Step Conversion of Biomass-Derived 5-Hydroxymethylfurfural to 1,2,6-Hexanetriol Over Ni-Co-Al Mixed Oxide Catalysts Under Mild Conditions[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2014,2(2):173-180.
APA	Yao, Shengxi,Wang, Xicheng,Jiang, Yijun,Wu, Feng,Chen, Xinguo,&Mu, Xindong.(2014).One-Step Conversion of Biomass-Derived 5-Hydroxymethylfurfural to 1,2,6-Hexanetriol Over Ni-Co-Al Mixed Oxide Catalysts Under Mild Conditions.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2(2),173-180.
MLA	Yao, Shengxi,et al."One-Step Conversion of Biomass-Derived 5-Hydroxymethylfurfural to 1,2,6-Hexanetriol Over Ni-Co-Al Mixed Oxide Catalysts Under Mild Conditions".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 2.2(2014):173-180.