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Selective Dehydration of Fructose to 5-hydroxymethylfurfural Catalyzed by Mesoporous AlSBA-15-SO3H in the Presence of Ionic Liquids
Xingcui Guo; Quan Cao; Yijun Jiang; Jing Guan; Xiaoyan Wang; Xindong Mu
2011
发表期刊Catalysis Letters
期号1页码:1-54
摘要Mesoporous SBA-15 materials functionalized with both propylsulfonic acid groups and aluminum species (AlSBA-15-SO3H) was synthesized via the conventional one-pot route and was used as a heterogeneous catalyst for the selective synthesis of 5-hydroxymethylfurfural (HMF) from dehydration of fructose using BmimCl as solvent. Some factors such as reaction time, reaction temperature and fructose concentration were investigated during the HMF synthesis procedure. The catalyst AlSBA-15-SO3H exhibits high fructose conversion (near 100%) and HMF selectivity (about 81%) with good stability in the HMF synthesis and appears to be a very suitable catalyst for the potential industrial process to produce HMF from renewable carbohydrates with high yield.
关键词5-hydroxymethylfurfural (Hmf) Fructose Dehydration Acid Catalysts Ionic Liquids
语种英语
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/626
专题绿色化学催化研究组
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GB/T 7714
Xingcui Guo,Quan Cao,Yijun Jiang,et al. Selective Dehydration of Fructose to 5-hydroxymethylfurfural Catalyzed by Mesoporous AlSBA-15-SO3H in the Presence of Ionic Liquids[J]. Catalysis Letters,2011(1):1-54.
APA Xingcui Guo,Quan Cao,Yijun Jiang,Jing Guan,Xiaoyan Wang,&Xindong Mu.(2011).Selective Dehydration of Fructose to 5-hydroxymethylfurfural Catalyzed by Mesoporous AlSBA-15-SO3H in the Presence of Ionic Liquids.Catalysis Letters(1),1-54.
MLA Xingcui Guo,et al."Selective Dehydration of Fructose to 5-hydroxymethylfurfural Catalyzed by Mesoporous AlSBA-15-SO3H in the Presence of Ionic Liquids".Catalysis Letters .1(2011):1-54.
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