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A single-ion gel polymer electrolyte based on polymeric lithium tartaric acid borate and its superior battery performance
Wang, Xuejiang; Liu, Zhihong; Kong, Qingshan; Jiang, Wen; Yao, Jianhua; Zhang, Chuanjian; Cui, Guanglei
2014-09-01
发表期刊SOLID STATE IONICS
卷号262期号:1页码:747-753
摘要

A single-ion gel polymer electrolyte of PLTB@PVDF-HFP (polymeric lithium tartaric acid borate@poly(vinylidene fluoride-co-hexafluoropropene)) was prepared and its ionic conductivity was optimized via solvent composition tailoring. It was manifested that the ethylene carbonate/dimethyl carbonate (EC/DMC) swollen PLTB@PVDF-HFP exhibited a superior lithium ionic conductivity at room temperature to that of the traditional liquid electrolyte system (1 M LiPF6/EC/DMC). The Li4Ti6O12/LiFePO4 cells using the EC/DMC swollen PLTB@PVDF-HFP as polymer electrolyte showed stable charge/discharge voltage profiles with small voltage hysteresis, preferable rate capability and excellent cycle performance at room temperature. These superior performances of EC/DMC swollen PLTB@PVDF-HFP could endow this class of gel polymer electrolyte a very promising alternative to state of the art liquid electrolyte system. (C) 2013 Elsevier B.V. All rights reserved.

文章类型Article
关键词Gel Polymer Electrolyte Lithium Salt Ionic Conductivity Single-ion Electrolyte Lithium Ion Battery
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.ssi.2013.09.007
关键词[WOS]POLYANIONIC SOLID ELECTROLYTES ; WEAK COULOMB TRAPS ; EXCHANGE MEMBRANES ; CONDUCTIVITY ; COMPOSITE ; LIBOB ; STABILITY ; SALT
收录类别SCI ; ISTP
语种英语
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Physical ; Physics, Condensed Matter
WOS记录号WOS:000338810500163
引用统计
被引频次:30[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/6241
专题仿生能源与储能系统团队
作者单位Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
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Wang, Xuejiang,Liu, Zhihong,Kong, Qingshan,et al. A single-ion gel polymer electrolyte based on polymeric lithium tartaric acid borate and its superior battery performance[J]. SOLID STATE IONICS,2014,262(1):747-753.
APA Wang, Xuejiang.,Liu, Zhihong.,Kong, Qingshan.,Jiang, Wen.,Yao, Jianhua.,...&Cui, Guanglei.(2014).A single-ion gel polymer electrolyte based on polymeric lithium tartaric acid borate and its superior battery performance.SOLID STATE IONICS,262(1),747-753.
MLA Wang, Xuejiang,et al."A single-ion gel polymer electrolyte based on polymeric lithium tartaric acid borate and its superior battery performance".SOLID STATE IONICS 262.1(2014):747-753.
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