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Title:
A single-ion gel polymer electrolyte based on polymeric lithium tartaric acid borate and its superior battery performance
Author: Wang, Xuejiang; Liu, Zhihong; Kong, Qingshan; Jiang, Wen; Yao, Jianhua; Zhang, Chuanjian; Cui GuangLei(崔光磊)
Source: SOLID STATE IONICS
Issued Date: 2014-09-01
Volume: 262, Issue:1, Pages:747-753
Keyword: Gel polymer electrolyte ; Lithium salt ; Ionic conductivity ; Single-ion electrolyte ; Lithium ion battery
DOI: 10.1016/j.ssi.2013.09.007
DOC Type: Article
English Abstract:

A single-ion gel polymer electrolyte of PLTB@PVDF-HFP (polymeric lithium tartaric acid borate@poly(vinylidene fluoride-co-hexafluoropropene)) was prepared and its ionic conductivity was optimized via solvent composition tailoring. It was manifested that the ethylene carbonate/dimethyl carbonate (EC/DMC) swollen PLTB@PVDF-HFP exhibited a superior lithium ionic conductivity at room temperature to that of the traditional liquid electrolyte system (1 M LiPF6/EC/DMC). The Li4Ti6O12/LiFePO4 cells using the EC/DMC swollen PLTB@PVDF-HFP as polymer electrolyte showed stable charge/discharge voltage profiles with small voltage hysteresis, preferable rate capability and excellent cycle performance at room temperature. These superior performances of EC/DMC swollen PLTB@PVDF-HFP could endow this class of gel polymer electrolyte a very promising alternative to state of the art liquid electrolyte system. (C) 2013 Elsevier B.V. All rights reserved.

WOS Headings: Science & Technology ; Physical Sciences
WOS Subject: Chemistry, Physical ; Physics, Condensed Matter
WOS Subject Extended: Chemistry ; Physics
WOS Keyword Plus: POLYANIONIC SOLID ELECTROLYTES ; WEAK COULOMB TRAPS ; EXCHANGE MEMBRANES ; CONDUCTIVITY ; COMPOSITE ; LIBOB ; STABILITY ; SALT
Indexed Type: SCI ; ISTP
Language: 英语
WOS ID: WOS:000338810500163
Citation statistics:
Content Type: 期刊论文
URI: http://ir.qibebt.ac.cn/handle/337004/6241
Appears in Collections:仿生能源与储能系统团队_期刊论文

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description.institution: Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China

Recommended Citation:
Wang, Xuejiang,Liu, Zhihong,Kong, Qingshan,et al. A single-ion gel polymer electrolyte based on polymeric lithium tartaric acid borate and its superior battery performance[J]. SOLID STATE IONICS,2014,262(1):747-753.
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