Acidic resin-catalyzed conversion of fructose into furan derivatives in low boiling point solvents | |
Hong Zhua; Quan Caoa; Chunhu Li; Xindong Mu | |
2011 | |
发表期刊 | Accepted Manuscript |
卷号 | 11期号:1页码:0-16 |
摘要 | Conversion of fructose into furan derivatives 5-hydroxymethylfurfural (HMF) and 5-methoxymethylfurfural (MMF) is performed in tetrahydrofuran (THF) and methanol-organic solvent systems, catalysed by an acidic resin Amberlyst-15. The melted fructose can be converted into HMF on the surface of the solid resin catalyst in the presence of THF as an extracting phase, which is a good solvent for HMF and other by-products. The solid resin catalyst can be reused eleven times without losing its catalytic ability, with an average HMF yield of approximately 50%. Upon the addition of methanol, the generated HMF can further react with methanol to form MMF, and the total yield of HMF and MMF could be promoted to 65%. GC-MS analysis confirms the formation of a small amount of methyl levulinate in methanolorganic solvent system. |
关键词 | Fructose 5-hydroxymethylfurfural 5-methoxymethylfurfural Methyl Levulinate Amberlyst-15 |
学科领域 | 绿色化学催化 |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/618 |
专题 | 绿色化学催化研究组 |
推荐引用方式 GB/T 7714 | Hong Zhua,Quan Caoa,Chunhu Li,et al. Acidic resin-catalyzed conversion of fructose into furan derivatives in low boiling point solvents[J]. Accepted Manuscript,2011,11(1):0-16. |
APA | Hong Zhua,Quan Caoa,Chunhu Li,&Xindong Mu.(2011).Acidic resin-catalyzed conversion of fructose into furan derivatives in low boiling point solvents.Accepted Manuscript,11(1),0-16. |
MLA | Hong Zhua,et al."Acidic resin-catalyzed conversion of fructose into furan derivatives in low boiling point solvents".Accepted Manuscript 11.1(2011):0-16. |
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