Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions

doi:10.1002/asia.201301327

	Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions
	Lv, Xiaoxia 1; Li, Liangjun1 ; Sun, Xiaoming 2; Zhang, Hongyu 2; Cai, Jinjun 1; Wang, Chao1 ; Tang, Sifu1 ; Zhao, Xuebo 1
	2014-03-01
发表期刊	CHEMISTRY-AN ASIAN JOURNAL
卷号	9 期号:3 页码:901-907
摘要	The microporous coordination polymer [Co(H2L)(bipy)(0.5)]2H(2)O (1, bipy=4,4-bipyridine) was synthesized on the basis of the V-shaped flexible diphosphonate ligand (2,4,6-trimethyl-1,3-phenylene)bis(methylene)diphosphonic acid (H4L) and the auxiliary bipy ligand under hydrothermal conditions. The structure of this compound was characterized by single-crystal X-ray diffraction. By joining the diphosphonate ligands and bipy through tetrahedral [CoO3N] clusters, a 2D square grid layered network was formed. Further stacking of these layers on the basis of - interactions resulted in a pseudo-3D microporous network with 1D channels running through the a axis. Gas sorption studies for CO2, H-2, CH4, N-2, and O-2 on this coordination polymer were performed, and the results revealed interesting dynamic and hysteresis sorption behavior toward H-2 at low temperature.
文章类型	Article
关键词	Coordination Polymers Diphosphonate Ligand Hysteresis Sorption Pi Interactions Polymers
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1002/asia.201301327
关键词[WOS]	METAL-ORGANIC FRAMEWORKS ; ZEOLITIC IMIDAZOLATE FRAMEWORKS ; BUILDING-BLOCKS ; ADSORPTION PROPERTIES ; SELECTIVE ADSORPTION ; MAGNETIC-PROPERTIES ; BRIDGING-LIGAND ; HYDROGEN ; CO2 ; TRANSFORMATION
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000331611900030
引用统计	被引频次：9[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6154
专题	储氢及新型纳孔材料团队（过去）
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Lab Hydrogen Storage & Novel Nanoporous Mat, Qingdao 266101, Peoples R China 2.China Univ Petr, Sch Chem Engn, State Key Lab Heavy Oil, Qingdao 266555, Peoples R China
推荐引用方式 GB/T 7714	Lv, Xiaoxia,Li, Liangjun,Sun, Xiaoming,et al. Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions[J]. CHEMISTRY-AN ASIAN JOURNAL,2014,9(3):901-907.
APA	Lv, Xiaoxia.,Li, Liangjun.,Sun, Xiaoming.,Zhang, Hongyu.,Cai, Jinjun.,...&Zhao, Xuebo.(2014).Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions.CHEMISTRY-AN ASIAN JOURNAL,9(3),901-907.
MLA	Lv, Xiaoxia,et al."Gas Sorption Studies on a Microporous Coordination Polymer Assembled from 2D Grid Layers by Strong pi-pi Interactions".CHEMISTRY-AN ASIAN JOURNAL 9.3(2014):901-907.