| Influence of aggregated morphology on carbon dioxide uptake of polythiophene conjugated organic networks | |
| Qiao, Shanlin1,2; Du, Zhengkun1; Huang, Wei1; Yang, Renqiang1 | |
| 2014-04-01 | |
| 发表期刊 | JOURNAL OF SOLID STATE CHEMISTRY
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| 卷号 | 212期号:1页码:69-72 |
| 摘要 | Two novel thiophene-based conjugated networks CMPs-TIT and CMPs-DTBT were designed and prepared with different steric configuration building blocks by FeCl3 oxidative coupling polymerization. UV-vis spectra, FE-SEM and TEM images showed CMPs-TTT and CMPs-DTBT having the different aggregated morphologies. After porous analysis and gas adsorption test, the result showed CO2 uptake capacity of CMPs-DTBT with amorphous aggregation model is 2.88 times and 2.66 times greater than that of CMPs-TTT with large lamellar structure model at 273 K and 298 K (1.0 bar), respectively. As a result, this communication proved that change the topological structure of the polymer can influence the CO2 adsorption capacity significantly. (C) 2014 Elsevier Inc. All rights reserved. |
| 文章类型 | Article |
| 关键词 | Pore Organic Polymer Polythiophene Steric Configuration Aggregated Morphology Carbon Dioxide Adsorption |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1016/j.jssc.2013.12.025 |
| 关键词[WOS] | MICROPOROUS POLYMERS ; HYDROGEN STORAGE ; CO2 CAPTURE ; INTRINSIC MICROPOROSITY ; SURFACE-AREA ; GAS-STORAGE ; FRAMEWORKS ; ADSORPTION ; SEPARATION ; OLIGOTHIOPHENES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
| WOS记录号 | WOS:000333071400011 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6131 |
| 专题 | 先进有机功能材料研究组 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiao, Shanlin,Du, Zhengkun,Huang, Wei,et al. Influence of aggregated morphology on carbon dioxide uptake of polythiophene conjugated organic networks[J]. JOURNAL OF SOLID STATE CHEMISTRY,2014,212(1):69-72. |
| APA | Qiao, Shanlin,Du, Zhengkun,Huang, Wei,&Yang, Renqiang.(2014).Influence of aggregated morphology on carbon dioxide uptake of polythiophene conjugated organic networks.JOURNAL OF SOLID STATE CHEMISTRY,212(1),69-72. |
| MLA | Qiao, Shanlin,et al."Influence of aggregated morphology on carbon dioxide uptake of polythiophene conjugated organic networks".JOURNAL OF SOLID STATE CHEMISTRY 212.1(2014):69-72. |
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| Influence of aggrega（1535KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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