Olefin epoxidation with hydrogen peroxide using octamolybdate-based self-separating catalysts

doi:10.1039/c4gc01411a

QIBEBT-IR > 多相催化转化研究组

	Olefin epoxidation with hydrogen peroxide using octamolybdate-based self-separating catalysts
	Zhou, Ming-Dong 1,2; Liu, Mei-Ju 1; Huang, Liang-Liang 1; Zhang, Jian 1; Wang, Jing-Yun 2; Li, Xue-Bing3 ; Kuehn, Fritz E.2; Zang, Shu-Liang 1
	2015
发表期刊	GREEN CHEMISTRY
卷号	17 期号:2 页码:1186-1193
摘要	Mo8O264- based organic polyoxomolybdate salts of general formula [Hmim](4)Mo8O26 (Hmim = 1-hexyl-3-methylimidazolium), [Dhmim](4)Mo8O26 (Dhmim = 1,2-dimethyl-3-hexylimidazolium) and [Hpy](4)Mo8O26 center dot H2O (Hpy = 1-hexylpyridinium) have been prepared and characterized. These compounds were applied as catalysts for olefin epoxidation using hydrogen peroxide (H2O2) as oxidant in CH3CN. The polyoxomolybdate salts exhibit excellent catalytic performance and are also self-separating, a great advantage for catalyst recycling. The catalysts can be reused for at least 10 runs without significant loss of activity.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c4gc01411a
关键词[WOS]	PHASE-TRANSFER CATALYSIS ; IONIC LIQUIDS ; CRYSTAL-STRUCTURE ; EFFICIENT EPOXIDATION ; PROPYLENE-OXIDE ; IN-SITU ; OXIDATION ; POLYOXOMETALATE ; COMPLEXES ; ALCOHOLS
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000349315200061
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6087
专题	多相催化转化研究组
作者单位	1.Liaoning Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Peoples R China 2.Tech Univ Munich, Catalysis Res Ctr, Mol Catalysis Chair Inorgan Chem, D-85747 Garching, Germany 3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Ming-Dong,Liu, Mei-Ju,Huang, Liang-Liang,et al. Olefin epoxidation with hydrogen peroxide using octamolybdate-based self-separating catalysts[J]. GREEN CHEMISTRY,2015,17(2):1186-1193.
APA	Zhou, Ming-Dong.,Liu, Mei-Ju.,Huang, Liang-Liang.,Zhang, Jian.,Wang, Jing-Yun.,...&Zang, Shu-Liang.(2015).Olefin epoxidation with hydrogen peroxide using octamolybdate-based self-separating catalysts.GREEN CHEMISTRY,17(2),1186-1193.
MLA	Zhou, Ming-Dong,et al."Olefin epoxidation with hydrogen peroxide using octamolybdate-based self-separating catalysts".GREEN CHEMISTRY 17.2(2015):1186-1193.