Construction of cadmium(II) and zinc(II) coordination frameworks based on 3,5-bis(benzoimidazo-1-ly)pyridine and carboxylate acids: Synthesis, crystal structures and photoluminescent properties

doi:10.1016/j.inoche.2013.09.033

QIBEBT-IR > 仿生与固态能源系统研究组

	Construction of cadmium(II) and zinc(II) coordination frameworks based on 3,5-bis(benzoimidazo-1-ly)pyridine and carboxylate acids: Synthesis, crystal structures and photoluminescent properties
	Xu, Jiakun 1,2; Sun, Xiaochun 3; Yan, Xingchen 2,4; Wang, Shuaiyu 1; Sun, Mi 1
	2013-11-01
发表期刊	INORGANIC CHEMISTRY COMMUNICATIONS
卷号	37 页码:49-53
摘要	Two new metal coordination polymers [Cd-2(ba)(4)(L)(2)](n) (1) and [Zn(tda)(L)](n) (2) [Hba = benzoic acid, H(2)tda = 2,5-thiophenedicarboxylic acid and L = 3,5-bis(benzoimidazo-1-ly)pyridine] have been successfully synthesized and structurally characterized by IR, elemental analysis. X-ray powder diffraction and X-ray single-crystal diffraction. For complex 1, two Cd(II) ions and four ba ligands form the dimetal clusters, which are further connected through the L ligands to give rise to a uninodal 3-connected hcb Shubnikov hexagonal plane net with the 6(3) topology. Complex 2 features the 3-connected topological net with 8(2) . 10 topology (so-called "tongue-and groove" structure). The Zn(II) node together with the four surrounding coordinated ligands form a typical T-shaped molecular bilayer motif, which is rarely reported previously. Their X-ray powder diffraction pattems were then carried out to confirm the validity of the crystal structures. In addition, the luminescent properties of 1 and 2 are investigated in the solid state at room temperature, and the thermogravimetric analyses were carried out to study the thermal stability of the two complexes. (C) 2013 Elsevier B.V. All rights reserved.
文章类型	Article
关键词	Hydrothermal Synthesis 3 Crystal Structure 5-bis(Benzoimidazo-1-ly)Pyridine Coordination Polymer Luminescence
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1016/j.inoche.2013.09.033
关键词[WOS]	METAL-ORGANIC FRAMEWORKS ; MAGNETIC-PROPERTIES ; POLYMERS ; LIGAND ; TOPOLOGIES ; DIVERSITY
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000328180900012
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/6045
专题	仿生与固态能源系统研究组
作者单位	1.Chinese Acad Fishery Sci, Yellow Sea Fisheries Res Inst, Minist Agr, Key Lab Sustainable Dev Marine Fisheries, Qingdao 266071, Peoples R China 2.Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Peoples R China 3.Natl Oceanog Ctr, Qingdao 266071, Peoples R China 4.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Xu, Jiakun,Sun, Xiaochun,Yan, Xingchen,et al. Construction of cadmium(II) and zinc(II) coordination frameworks based on 3,5-bis(benzoimidazo-1-ly)pyridine and carboxylate acids: Synthesis, crystal structures and photoluminescent properties[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2013,37:49-53.
APA	Xu, Jiakun,Sun, Xiaochun,Yan, Xingchen,Wang, Shuaiyu,&Sun, Mi.(2013).Construction of cadmium(II) and zinc(II) coordination frameworks based on 3,5-bis(benzoimidazo-1-ly)pyridine and carboxylate acids: Synthesis, crystal structures and photoluminescent properties.INORGANIC CHEMISTRY COMMUNICATIONS,37,49-53.
MLA	Xu, Jiakun,et al."Construction of cadmium(II) and zinc(II) coordination frameworks based on 3,5-bis(benzoimidazo-1-ly)pyridine and carboxylate acids: Synthesis, crystal structures and photoluminescent properties".INORGANIC CHEMISTRY COMMUNICATIONS 37(2013):49-53.