| A Highly Efficient Synthesis of Optically Active Ferrocenylethylamines via Hydride Reduction of Chiral Ferrocenylketimines | |
| Qian, Hengyu1,2; Yan, Shihai3; Cui, Xiuling1; Pi, Chao1; Liu, Cheng1; Wu, Yangjie1 | |
| 2013-08-01 | |
| 发表期刊 | CHINESE JOURNAL OF CHEMISTRY
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| 卷号 | 31期号:8页码:992-996 |
| 摘要 | Due to using (R)- or (S)--methylbenzylamine as a chiral auxiliary, and low-temperature regime for reduction of the intermediate ferrocenyl-mono- or 1,1-bis-ketimines, the corresponding secondary mono- or 1,1-bis-amines were prepared with high diastereoselectivity. Removal of the -methylbenzyl group afforded the optically active primary mono- and bis-ferrocenylethylamines in high yields. The absolute configuration of (R,R)-3a and (S,S)-3b was determined by X-ray single crystal diffraction. |
| 文章类型 | Article |
| 关键词 | Chiral Reduction Ferrocenylketimine Diastereoselectivity Ferrocenylethylamine |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1002/cjoc.201300211 |
| 关键词[WOS] | ENANTIOSELECTIVE SYNTHESIS ; DIASTEREOSELECTIVE ADDITION ; ORGANOLITHIUM COMPOUNDS ; ASYMMETRIC CATALYSIS ; FERROCENE LIGANDS ; STEP SYNTHESIS ; 1-FERROCENYLALKYLAMINES ; ACETYLFERROCENE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| WOS记录号 | WOS:000327738500004 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6036 |
| 专题 | 蛋白质设计研究组 |
| 作者单位 | 1.Zhengzhou Univ, Dept Chem, Henan Key Lab Chem Biol & Organ Chem, Key Lab Appl Chem Henan Univ, Zhengzhou 450052, Henan, Peoples R China 2.Zhengzhou Univ Light Ind, Sch Mat & Chem Engn, Henan Key Lab Surface & Interface Sci, Zhengzhou 450002, Henan, Peoples R China 3.Chinese Acad Sci, Inst Bioenergy & Bioproc Technol, Lab Biofuel, Qingdao 266101, Shandong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qian, Hengyu,Yan, Shihai,Cui, Xiuling,et al. A Highly Efficient Synthesis of Optically Active Ferrocenylethylamines via Hydride Reduction of Chiral Ferrocenylketimines[J]. CHINESE JOURNAL OF CHEMISTRY,2013,31(8):992-996. |
| APA | Qian, Hengyu,Yan, Shihai,Cui, Xiuling,Pi, Chao,Liu, Cheng,&Wu, Yangjie.(2013).A Highly Efficient Synthesis of Optically Active Ferrocenylethylamines via Hydride Reduction of Chiral Ferrocenylketimines.CHINESE JOURNAL OF CHEMISTRY,31(8),992-996. |
| MLA | Qian, Hengyu,et al."A Highly Efficient Synthesis of Optically Active Ferrocenylethylamines via Hydride Reduction of Chiral Ferrocenylketimines".CHINESE JOURNAL OF CHEMISTRY 31.8(2013):992-996. |
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| A Highly Efficient S（889KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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