| Synthesis, Structures, and Properties of Two Novel Coordination Polymers with a V-shaped Diphosphonate Ligand | |
Lv, Xiaoxia1,2; Tang, Sifu1 ; Li, Liangjun1,2; Xu, Xianrui1,2; Zhao, Xuebo1
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| 2013-08-01 | |
| 发表期刊 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
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| 卷号 | 639期号:10页码:1845-1849 |
| 摘要 | Two novel coordination polymers, [Cu(H2L)(bipy)(H2O)(2)]center dot H2O (1) and [Ni-2(H2L)(bipy)(2.5)(H2O)(6)]center dot(H2L)center dot 7H(2)O (2) with the V-shaped diphosphonate ligand (2,4,6-trimethyl-1,3-phenylene) bis(methylene) diphosphonic acid (H4L) were synthesized via hydrothermal reactions in the presence of auxiliary ligand 4,4'-bipyridine. Their structures were determined by single-crystal X-ray diffraction and further characterized by elemental analysis, infrared spectroscopy (IR), and thermogravimetric analysis (TGA). Compound 1 crystallizes in the Pnma space group and compound 2 crystallizes in the P2(1)2(1)2 space group. They display square-grid layer and bilayer two-dimensional network, respectively. |
| 文章类型 | Article |
| 关键词 | Diphosphonate Ligand V-shape Crystal Structure X-ray Diffraction Infrared Spectroscopy |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1002/zaac.201300185 |
| 关键词[WOS] | METAL-ORGANIC FRAMEWORK ; TRINUCLEAR (NICUNIII)-CU-II-NI-II COMPLEXES ; ZEOLITIC IMIDAZOLATE FRAMEWORKS ; MAGNETIC-PROPERTIES ; CRYSTAL-STRUCTURE ; SMALL MOLECULES ; SEPARATION ; CHAIN ; CO2 ; CAPTURE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| WOS记录号 | WOS:000327704000024 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/6014 |
| 专题 | 多相催化转化研究组 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lv, Xiaoxia,Tang, Sifu,Li, Liangjun,et al. Synthesis, Structures, and Properties of Two Novel Coordination Polymers with a V-shaped Diphosphonate Ligand[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2013,639(10):1845-1849. |
| APA | Lv, Xiaoxia,Tang, Sifu,Li, Liangjun,Xu, Xianrui,&Zhao, Xuebo.(2013).Synthesis, Structures, and Properties of Two Novel Coordination Polymers with a V-shaped Diphosphonate Ligand.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,639(10),1845-1849. |
| MLA | Lv, Xiaoxia,et al."Synthesis, Structures, and Properties of Two Novel Coordination Polymers with a V-shaped Diphosphonate Ligand".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 639.10(2013):1845-1849. |
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| Synthesis, Structure（642KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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