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Syntheses, Structures, and Properties of Copper(II), Cobalt(II), and Cadmium(II) Complexes with Flexible Multicarboxylate Ligand
Xu, Xianrui1,2; Pan, Xiaobo1; Tang, Sifu1; Lv, Xiaoxia1,2; Li, Liangjun1,2; Zhao, Xuebo1
2013-05-01
发表期刊ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
卷号639期号:6页码:967-973
摘要

Three new coordination polymers, namely, [CuL0.5] (1), [Co(H2L)(H2O)2][H2O] (2), and [(CdCl)0.5Cd0.25(H2L)0.5] (3) were synthesized under hydrothermal conditions from the corresponding CuII, CoII, and CdII salts with a multidentate ligand of 2,2,2,2-[2,3,5,6-tetramethyl-1,4-phenylenebis(methylenenitrilo)]tetraacetic acid (H4L). The complexes were characterized by single-crystal X-ray diffraction, IR, thermogravimetric, and elemental analyses. Complex 1 crystallizes in the orthorhombic space group Pbca and has a three-dimensional architecture with infinite two-dimensional networks linked together by weak CuO interactions. Complex 2 crystallizes in the monoclinic space group P2(1) and displays a 2D network. Complex 3 crystallizes in the tetragonal space group P4(2)/ncm and exhibits an infinite 3D architecture that has unusual [Cd2(CO2)4Cl2] dinuclear paddle-wheel units and [Cd(CO2)4] dodecahedron units. The results showed that the coordination arrangement of central metal atoms and the conformation and coordination mode of organic ligands play an important role in determining the structure of the complexes. The luminescence property of complex 3 was studied in the solid state at room temperature.

文章类型Article
关键词Crystal Structure Flexible Ligand Hydrothermal Synthesis Coordination Polymers Photoluminescence
WOS标题词Science & Technology ; Physical Sciences
DOI10.1002/zaac.201300126
关键词[WOS]METAL-ORGANIC FRAMEWORKS ; COORDINATION POLYMERS ; HYDROTHERMAL SYNTHESIS ; CRYSTAL-STRUCTURES ; DONOR LIGANDS ; N-DONOR ; ACID ; CONSTRUCTION ; DESIGN ; CHAINS
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
WOS记录号WOS:000319424400017
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/6011
专题多相催化转化研究组
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Xu, Xianrui,Pan, Xiaobo,Tang, Sifu,et al. Syntheses, Structures, and Properties of Copper(II), Cobalt(II), and Cadmium(II) Complexes with Flexible Multicarboxylate Ligand[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2013,639(6):967-973.
APA Xu, Xianrui,Pan, Xiaobo,Tang, Sifu,Lv, Xiaoxia,Li, Liangjun,&Zhao, Xuebo.(2013).Syntheses, Structures, and Properties of Copper(II), Cobalt(II), and Cadmium(II) Complexes with Flexible Multicarboxylate Ligand.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,639(6),967-973.
MLA Xu, Xianrui,et al."Syntheses, Structures, and Properties of Copper(II), Cobalt(II), and Cadmium(II) Complexes with Flexible Multicarboxylate Ligand".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 639.6(2013):967-973.
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