Pd(OAc)2@SBA-15/PrEn nanoreactor: a highly active, reusable and selective phosphine-free catalyst for Suzuki-Miyaura cross-coupling reaction in aqueous media

doi:10.1002/aoc.2986

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	Pd(OAc)2@SBA-15/PrEn nanoreactor: a highly active, reusable and selective phosphine-free catalyst for Suzuki-Miyaura cross-coupling reaction in aqueous media
	Rostamnia, Sadegh 1; Xin, Hongchuan 2
	2013-06-01
发表期刊	APPLIED ORGANOMETALLIC CHEMISTRY
卷号	27 期号:6 页码:348-352
摘要	A series of ordered mesoporous organic-inorganic hybrid material was designed by using the amine-functionalized SBA-15 (PdX2@SBA-15/NY, Y=1, 2) as solid support for palladium complexes. Among them, the Pd(OAc)2/ethylenediamine complex encapsulated into SBA-15 (Pd(OAc)2@SBA-15/PrEn or Pd(OAc)2@SBA-15/PrNHEtNH2) exhibits higher activity and selectivity toward Suzuki cross-coupling reaction under aerobic conditions and water solvent mixture. The SBA-15/PrEn supported palladium pre-catalyst could be separated easily from reaction products and used repetitively several times, showing its superiority over homogeneous catalysts for industrial and chemical applications. Copyright (c) 2013 John Wiley & Sons, Ltd.
文章类型	Article
关键词	Suzuki-miyaura Cross-coupling Heterogeneous Catalyst Mesoporous Nanoreactor Pd@sba-15 Pren Transition Metal Complex
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1002/aoc.2986
关键词[WOS]	CARBAPALLADACYCLE COMPLEX ; HETEROGENEOUS CATALYST ; PALLADIUM CATALYST ; MESOPOROUS SILICA ; HECK REACTION ; WATER ; EFFICIENT ; GREEN ; NANOPARTICLES ; DERIVATIVES
收录类别	SCI ; CCR
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Applied ; Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000319516500006
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/5995
专题	科技处
作者单位	1.Univ Maragheh, Dept Chem, ONG, Fac Sci, Maragheh, Iran 2.Chinese Acad Sci, Key Lab Biofuels, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Rostamnia, Sadegh,Xin, Hongchuan. Pd(OAc)2@SBA-15/PrEn nanoreactor: a highly active, reusable and selective phosphine-free catalyst for Suzuki-Miyaura cross-coupling reaction in aqueous media[J]. APPLIED ORGANOMETALLIC CHEMISTRY,2013,27(6):348-352.
APA	Rostamnia, Sadegh,&Xin, Hongchuan.(2013).Pd(OAc)2@SBA-15/PrEn nanoreactor: a highly active, reusable and selective phosphine-free catalyst for Suzuki-Miyaura cross-coupling reaction in aqueous media.APPLIED ORGANOMETALLIC CHEMISTRY,27(6),348-352.
MLA	Rostamnia, Sadegh,et al."Pd(OAc)2@SBA-15/PrEn nanoreactor: a highly active, reusable and selective phosphine-free catalyst for Suzuki-Miyaura cross-coupling reaction in aqueous media".APPLIED ORGANOMETALLIC CHEMISTRY 27.6(2013):348-352.