Direct Synthesis of Al-SBA-15 at High Aging Temperature without Mineral Acid

doi:10.3969/j.issn.1001-4861.2013.00.248

QIBEBT-IR > 多相催化转化研究组

	Direct Synthesis of Al-SBA-15 at High Aging Temperature without Mineral Acid
	Xu Yan 1,2; Xing Li-Shu 1,2; Li Xiang-Ping 2; Shi Lei 3; Li Xue-Bing2 ; Lin Sen 2; Li Ming-Shi 1
	2013-09-10
发表期刊	CHINESE JOURNAL OF INORGANIC CHEMISTRY
卷号	29 期号:9 页码:1849-1855
摘要	Al-SBA-15 with a rod-like morphology and well-ordered mesostructure was hydrothermally synthesized through a one-step approach in an environmentally friendly medium by using triblock copolymer Pluronic P123 as a structure-directing agent. The influence of aging temperature and silica-alumina species co-hydrolysis on the morphologies and structural properties of the resultant materials were investigated by XRD, IR, SEM, TEM and nitrogen adsorption-desorption techniques at 77 K. Compared to silica-alumina co-hydrolysis, the aging temperature plays an important role in the formation of the ordered mesostructure. The mesopores are widened and the wall thickness becomes thinner when the aging temperature is increased. The particles have well-defined rod-like morphology with the uniform particle size from 2 to 4 m and the diameter in the range of 400 similar to 600 nm. The Si/Al molar ratio of the final Al-SBA-15 samples will be obviously higher if the time for silica-alumina co-hydrolysis is longer than 20 h.
文章类型	Article
关键词	Al-sba-15 Acid-free Hydrothermal Synthesis Mesoporous Materials Morphology Pore Structure
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.3969/j.issn.1001-4861.2013.00.248
关键词[WOS]	ORDERED MESOPOROUS SILICA ; HYDROCARBON SURFACTANT MIXTURES ; MOLECULAR-SIEVES ; ONE-POT ; SBA-15 ; ENVIRONMENT ; MCM-41 ; AL
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000330272000012
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/5988
专题	多相催化转化研究组
作者单位	1.Changzhou Univ, Inst Petrochem Technol, Changzhou 213164, Jiangsu, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Shandong, Peoples R China 3.Shandong Polytech Univ, Key Lab Fine Chem Univ Shandong, Jinan 250353, Peoples R China
推荐引用方式 GB/T 7714	Xu Yan,Xing Li-Shu,Li Xiang-Ping,et al. Direct Synthesis of Al-SBA-15 at High Aging Temperature without Mineral Acid[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2013,29(9):1849-1855.
APA	Xu Yan.,Xing Li-Shu.,Li Xiang-Ping.,Shi Lei.,Li Xue-Bing.,...&Li Ming-Shi.(2013).Direct Synthesis of Al-SBA-15 at High Aging Temperature without Mineral Acid.CHINESE JOURNAL OF INORGANIC CHEMISTRY,29(9),1849-1855.
MLA	Xu Yan,et al."Direct Synthesis of Al-SBA-15 at High Aging Temperature without Mineral Acid".CHINESE JOURNAL OF INORGANIC CHEMISTRY 29.9(2013):1849-1855.