Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties

doi:10.1002/ejic.201200923

QIBEBT-IR > 先进有机功能材料研究组

	Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties
	Jiang, Fei 1,2; Wang, Jun1 ; Li, Jianzhong 1; Wang, Ning 1; Bao, Xichang1 ; Wang, Ting 1; Yang, Ying1 ; Lan, Zhenggang 1; Yang, Renqiang 1
	2013
发表期刊	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
期号	3 页码:375-380
摘要	Functional nanosized cage complexes with an octahedral framework have been synthesized by the facile self-assembly reactions of six 90 PdII-containing compounds {[Pd(dppf)(OTf)(2)] or [Pd(PPh3)(OTf)(2)], dppf = 1,1'-bis(diphenylphosphanyl) ferrocene, OTf = trifluoromethylsulfonate} and four 120 degrees functional tritopic ligands [2,4,6-tri(4-pyridyl)-1,3,5-triazine] in acetone. Diffusion-ordered NMR spectroscopy (DOSY) and AFM images clarify the formation of 3-4 nm nanoparticles. These highly symmetrical cage complexes are discrete, face-directed, functional nanoparticles with symmetrical octahedral structures. The self-assembled functional cage complexes exhibit interesting electrochemical activities, and thus will potentially be useful in the catalysis of redox reactions, the encapsulation of sizeable guest molecules and the control of organic synthetic reactions.
文章类型	Article
关键词	Self-assembly Nanostructures Cage Compounds Electrochemistry Palladium n Ligands
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1002/ejic.201200923
关键词[WOS]	COORDINATION CAGE ; MOLECULAR ARCHITECTURE ; BIOMIMETIC MATERIALS ; BUILDING-BLOCKS ; METALLODENDRIMERS ; CONSTRUCTION ; CHEMISTRY ; PHOTODIMERIZATION ; INCLUSION ; COPOLYMER
收录类别	SCI
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:000316284700006
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/5943
专题	先进有机功能材料研究组
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Jiang, Fei,Wang, Jun,Li, Jianzhong,et al. Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2013(3):375-380.
APA	Jiang, Fei.,Wang, Jun.,Li, Jianzhong.,Wang, Ning.,Bao, Xichang.,...&Yang, Renqiang.(2013).Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(3),375-380.
MLA	Jiang, Fei,et al."Supramolecular Assemblies with Symmetrical Octahedral Structures - Synthesis, Characterization, and Electrochemical Properties".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .3(2013):375-380.