Synthesis, characterization of hetero-bimetallic complex and application in the polymerization of ε-caprolactone

	Synthesis, characterization of hetero-bimetallic complex and application in the polymerization of ε-caprolactone
	Xiaobo Pan; Ai Liu; Lihui Yao; Lei Wang; Jinfeng Zhang; Jincai Wu; Xuebo Zhao, Chu-Chieh Lin
	2011
发表期刊	Inorganic Chemistry Communications
卷号	14 期号:1 页码:763–766
摘要	The reaction of 2,2′-ethylidenebis(4,6-di-tert-butylphenol)(EDBP-H2) with sodium, Al(Me)3 and BnOH with a molar of ratio of 1:1:1:1 in THF gives hetero-bimetallic complex of [(EDBP)Al(CH3)(μ2-OBn)Na(THF)3](1) in 85% yield. In order to investigate the different anion effects on the ROP of ε-caprolactone, complexes [(EDBP)2Al][(Li)(THF)2] (2) and [(EDBP)2Al][(Na)(THF)2] (3) were prepared in an analogous manner to that of 1 in 63% and 71% yields respectively. Experimental results show that hetero-bimetallic complex 1 is an efficient catalyst for the ring-opening polymerization of ε-caprolactone.
关键词	Hetero-bimetallic Complex Ε-caprolactone Catalyst Ring-opening Polymerization
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/560
专题	储氢及新型纳孔材料团队（过去）
推荐引用方式 GB/T 7714	Xiaobo Pan,Ai Liu,Lihui Yao,et al. Synthesis, characterization of hetero-bimetallic complex and application in the polymerization of ε-caprolactone[J]. Inorganic Chemistry Communications,2011,14(1):763–766.
APA	Xiaobo Pan.,Ai Liu.,Lihui Yao.,Lei Wang.,Jinfeng Zhang.,...&Xuebo Zhao, Chu-Chieh Lin.(2011).Synthesis, characterization of hetero-bimetallic complex and application in the polymerization of ε-caprolactone.Inorganic Chemistry Communications,14(1),763–766.
MLA	Xiaobo Pan,et al."Synthesis, characterization of hetero-bimetallic complex and application in the polymerization of ε-caprolactone".Inorganic Chemistry Communications 14.1(2011):763–766.

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