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Annealing-free P3HT:PCBM-based organic solar cells via two halohydrocarbons additives with similar boiling points
Bao, Xichang1; Wang, Ting1; Yang, Ailing2; Yang, Chunpeng1; Dou, Xiaowei1; Chen, Weichao1; Wang, Ning1; Yang, Renqiang1
2014-02-01
发表期刊MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
卷号180期号:2014页码:7-11
摘要Efficient annealing-free inverted bulk heterojunction (BHJ) organic solar cells based on poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C-61-butyric acid methyl ester (PCBM) (1:1, w/w) have been obtained using two easily accessible halohydrocarbons (1,6-dibromohexane (DBH) and 1-bromodecane (BD)) with the same boiling points as solvent additives. The devices treated with 2.5 wt% additives removed the grain boundary of the large PCBM-rich phase, resulting in more-uniform film morphology on the nanoscale. The more-uniform film morphology greatly improved the short circuit current density of the devices. Finally, PCEs of the devices processed with DBH and BD reached 3.81% and 3.68%, respectively. Both additives with almost the same boiling points had a similar impact on device performance, despite of different chemical structures with different polarities and other physical properties. (C) 2013 Elsevier B.V. All rights reserved.
文章类型Article
关键词Organic Solar Cells Annealing-free Halohydrocarbons Additives Interpenetrating Networks
学科领域先进功能有机材料
WOS标题词Science & Technology ; Technology ; Physical Sciences
DOI10.1016/j.mseb.2013.10.009
关键词[WOS]POLYMER PHOTOVOLTAIC CELLS ; MORPHOLOGY CONTROL ; PERFORMANCE ; EFFICIENCY ; FULLERENE ; BLENDS ; CRYSTALLIZATION ; FILMS ; POLY(3-HEXYLTHIOPHENE) ; NETWORK
收录类别SCI
语种英语
WOS研究方向Materials Science ; Physics
WOS类目Materials Science, Multidisciplinary ; Physics, Condensed Matter
WOS记录号WOS:000331499400002
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/1712
专题先进有机功能材料研究组
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
2.Ocean Univ China, Dept Phys, Qingdao 266100, Peoples R China
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Bao, Xichang,Wang, Ting,Yang, Ailing,et al. Annealing-free P3HT:PCBM-based organic solar cells via two halohydrocarbons additives with similar boiling points[J]. MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS,2014,180(2014):7-11.
APA Bao, Xichang.,Wang, Ting.,Yang, Ailing.,Yang, Chunpeng.,Dou, Xiaowei.,...&Yang, Renqiang.(2014).Annealing-free P3HT:PCBM-based organic solar cells via two halohydrocarbons additives with similar boiling points.MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS,180(2014),7-11.
MLA Bao, Xichang,et al."Annealing-free P3HT:PCBM-based organic solar cells via two halohydrocarbons additives with similar boiling points".MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS 180.2014(2014):7-11.
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