The preparation and properties of bulk-heterojunction organic solar cells with indole-containing fulleropyrrolidine derivatives as acceptors | |
Zhang, Xiaona1,2; Sun, Liang1,3; Zheng, Wei2; Bao, Xichang1; Wang, Ning1; Wang, Ting1; Yang, Renqiang1 | |
2013-11-18 | |
发表期刊 | TETRAHEDRON |
卷号 | 69期号:46页码:9544-9550 |
摘要 | Two indole-containing fullerene derivatives, N-hydrogen-2-[3-(N-2-ethylhexylindolyl)][60]fulleropyrrolidine (EHIHC60P), and N-(2-ethylhexylindolyl))-2-[3-(N-2-ethylhexylindoly1)][60]fulleropyrrolidine (DEHIC60P) were synthesized by the typical Prato reaction. The absorption spectra, electrochemical properties of the two compounds were measured. Inverted solar cells were fabricated with the structure of ITO/ZnO/poly(3-hexylthiophene) (P3HT):fullerene derivatives/MoO3/Ag. The highest power conversion efficiencies (PCEs) of 3.32% and 3.23% were obtained for P3HT/EHIHC60P and P3HT/DEHIC60P based solar cells at the composite ratio of 1:1 after the active layers were annealed at 150 degrees C under inert atmosphere, with a open-circuit voltage (V-oc) of 0.66 V and 0.74 V, respectively. For comparison, the device based on P3HT/PCBM at the same conditions showed the PCE of 328%, with a V-oc of 0.61 V. The influence on the photovoltaic property of the fullerene derivatives, which was induced by some subtle changes in the chemical structure was compared and discussed. (c) 2013 Elsevier Ltd. All rights reserved. |
文章类型 | Article |
关键词 | Photovoltaic Effect Fullerene Derivative Indole Electron Acceptor |
学科领域 | 先进功能有机材料 |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1016/j.tet2013.09.046 |
关键词[WOS] | SUBSTITUTED FULLERENE DERIVATIVES ; OPEN-CIRCUIT VOLTAGE ; PHOTOVOLTAIC PROPERTIES ; SOLVENT ADDITIVES ; ENERGY-LEVEL ; SIDE-CHAINS ; POLYMER ; PERFORMANCE ; EFFICIENT ; BISADDUCT |
收录类别 | SCI ; IC |
语种 | 英语 |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
WOS记录号 | WOS:000326768800003 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/1710 |
专题 | 先进有机功能材料研究组 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Harbin Univ Sci & Technol, Coll Mat Sci & Engn, Harbin 150080, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Xiaona,Sun, Liang,Zheng, Wei,et al. The preparation and properties of bulk-heterojunction organic solar cells with indole-containing fulleropyrrolidine derivatives as acceptors[J]. TETRAHEDRON,2013,69(46):9544-9550. |
APA | Zhang, Xiaona.,Sun, Liang.,Zheng, Wei.,Bao, Xichang.,Wang, Ning.,...&Yang, Renqiang.(2013).The preparation and properties of bulk-heterojunction organic solar cells with indole-containing fulleropyrrolidine derivatives as acceptors.TETRAHEDRON,69(46),9544-9550. |
MLA | Zhang, Xiaona,et al."The preparation and properties of bulk-heterojunction organic solar cells with indole-containing fulleropyrrolidine derivatives as acceptors".TETRAHEDRON 69.46(2013):9544-9550. |
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