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The preparation and properties of bulk-heterojunction organic solar cells with indole-containing fulleropyrrolidine derivatives as acceptors
Zhang, Xiaona1,2; Sun, Liang1,3; Zheng, Wei2; Bao, Xichang1; Wang, Ning1; Wang, Ting1; Yang, Renqiang1
2013-11-18
发表期刊TETRAHEDRON
卷号69期号:46页码:9544-9550
摘要Two indole-containing fullerene derivatives, N-hydrogen-2-[3-(N-2-ethylhexylindolyl)][60]fulleropyrrolidine (EHIHC60P), and N-(2-ethylhexylindolyl))-2-[3-(N-2-ethylhexylindoly1)][60]fulleropyrrolidine (DEHIC60P) were synthesized by the typical Prato reaction. The absorption spectra, electrochemical properties of the two compounds were measured. Inverted solar cells were fabricated with the structure of ITO/ZnO/poly(3-hexylthiophene) (P3HT):fullerene derivatives/MoO3/Ag. The highest power conversion efficiencies (PCEs) of 3.32% and 3.23% were obtained for P3HT/EHIHC60P and P3HT/DEHIC60P based solar cells at the composite ratio of 1:1 after the active layers were annealed at 150 degrees C under inert atmosphere, with a open-circuit voltage (V-oc) of 0.66 V and 0.74 V, respectively. For comparison, the device based on P3HT/PCBM at the same conditions showed the PCE of 328%, with a V-oc of 0.61 V. The influence on the photovoltaic property of the fullerene derivatives, which was induced by some subtle changes in the chemical structure was compared and discussed. (c) 2013 Elsevier Ltd. All rights reserved.
文章类型Article
关键词Photovoltaic Effect Fullerene Derivative Indole Electron Acceptor
学科领域先进功能有机材料
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.tet2013.09.046
关键词[WOS]SUBSTITUTED FULLERENE DERIVATIVES ; OPEN-CIRCUIT VOLTAGE ; PHOTOVOLTAIC PROPERTIES ; SOLVENT ADDITIVES ; ENERGY-LEVEL ; SIDE-CHAINS ; POLYMER ; PERFORMANCE ; EFFICIENT ; BISADDUCT
收录类别SCI ; IC
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Organic
WOS记录号WOS:000326768800003
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/1710
专题先进有机功能材料研究组
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
2.Harbin Univ Sci & Technol, Coll Mat Sci & Engn, Harbin 150080, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Zhang, Xiaona,Sun, Liang,Zheng, Wei,et al. The preparation and properties of bulk-heterojunction organic solar cells with indole-containing fulleropyrrolidine derivatives as acceptors[J]. TETRAHEDRON,2013,69(46):9544-9550.
APA Zhang, Xiaona.,Sun, Liang.,Zheng, Wei.,Bao, Xichang.,Wang, Ning.,...&Yang, Renqiang.(2013).The preparation and properties of bulk-heterojunction organic solar cells with indole-containing fulleropyrrolidine derivatives as acceptors.TETRAHEDRON,69(46),9544-9550.
MLA Zhang, Xiaona,et al."The preparation and properties of bulk-heterojunction organic solar cells with indole-containing fulleropyrrolidine derivatives as acceptors".TETRAHEDRON 69.46(2013):9544-9550.
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