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Fractionation of the main components of corn stover by formic acid and enzymatic saccharification of solid residue
Yu, Guang; Li, Bin; Liu, Chao; Zhang, Yuedong; Wang, Haisong; Mu, Xindong
2013-10-01
发表期刊INDUSTRIAL CROPS AND PRODUCTS
卷号50期号:50页码:750-757
摘要In this work, three main components (cellulose, hemicellulose, and lignin) of corn stover were fraction-ated effectively by formic acid. The effects of reaction temperature and time on the fractionation wereinvestigated. It was found that the suitable conditions for the fractionation of corn stover were: the formicacid concentration was 88 wt.%, the ratio of solid to liquid was 1:13, and the treatment temperature was80◦C with the duration of 3 h. Under such conditions, the retention yield of cellulose, extraction yields ofhemicellulose and lignin were 89.5%, 79.8% and 65.6%, respectively. Subsequently, the enzymatic hydrol-ysis of the solid residue was conducted by using the enzyme mixture of cellulase (20 FPU/g dry substrate)and -glucosidase (10 IU/g dry substrate). The enzymatic hydrolysis rate of glucan and xylan could reach62.8% and 79.4%, respectively. In addition, to study the property changes of corn stover before and aftertreatment, SEM, XRD and TGA analyses were performed, and the lignin extracted by formic acid was alsocharacterized by TGA and GPC; In this work, three main components (cellulose, hemicellulose, and lignin) of corn stover were fractionated effectively by formic acid. The effects of reaction temperature and time on the fractionation were investigated. It was found that the suitable conditions for the fractionation of corn stover were: the formic acid concentration was 88 wt.%, the ratio of solid to liquid was 1:13, and the treatment temperature was 80 C with the duration of 3 h. Under such conditions, the retention yield of cellulose, extraction yields of hemicellulose and lignin were 89.5%, 79.8% and 65.6%, respectively. Subsequently, the enzymatic hydrolysis of the solid residue was conducted by using the enzyme mixture of cellulase (20 FPU/g dry substrate) and beta-glucosidase (10IU/g dry substrate). The enzymatic hydrolysis rate of glucan and xylan could reach 62.8% and 79.4%, respectively. In addition, to study the property changes of corn stover before and after treatment, SEM, XRD and TGA analyses were performed, and the lignin extracted bylformic acid was also characterized by TGA and GPC. (C) 2013 Elsevier B.V. All rights reserved.
文章类型Article
关键词Corn Stover Formic Acid Fractionation Enzymatic Saccharification
学科领域绿色化学催化
WOS标题词Science & Technology ; Life Sciences & Biomedicine
DOI10.1016/j.indcrop.2013.08.053
关键词[WOS]PRETREATMENT ; CELLULOSE ; LIGNIN ; HYDROLYSIS ; EXTRACTION ; EXPLOSION ; PYROLYSIS ; CATALYSTS ; AMMONIA ; BIOMASS
收录类别SCI
语种英语
WOS研究方向Agriculture
WOS类目Agricultural Engineering ; Agronomy
WOS记录号WOS:000326903600101
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/1654
专题绿色化学催化研究组
作者单位Chinese Acad Sci, Key Lab Biofuels, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
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Yu, Guang,Li, Bin,Liu, Chao,et al. Fractionation of the main components of corn stover by formic acid and enzymatic saccharification of solid residue[J]. INDUSTRIAL CROPS AND PRODUCTS,2013,50(50):750-757.
APA Yu, Guang,Li, Bin,Liu, Chao,Zhang, Yuedong,Wang, Haisong,&Mu, Xindong.(2013).Fractionation of the main components of corn stover by formic acid and enzymatic saccharification of solid residue.INDUSTRIAL CROPS AND PRODUCTS,50(50),750-757.
MLA Yu, Guang,et al."Fractionation of the main components of corn stover by formic acid and enzymatic saccharification of solid residue".INDUSTRIAL CROPS AND PRODUCTS 50.50(2013):750-757.
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