Fractionation of the main components of corn stover by formic acid and enzymatic saccharification of solid residue | |
Yu, Guang; Li, Bin; Liu, Chao; Zhang, Yuedong; Wang, Haisong; Mu, Xindong | |
2013-10-01 | |
发表期刊 | INDUSTRIAL CROPS AND PRODUCTS |
卷号 | 50期号:50页码:750-757 |
摘要 | In this work, three main components (cellulose, hemicellulose, and lignin) of corn stover were fraction-ated effectively by formic acid. The effects of reaction temperature and time on the fractionation wereinvestigated. It was found that the suitable conditions for the fractionation of corn stover were: the formicacid concentration was 88 wt.%, the ratio of solid to liquid was 1:13, and the treatment temperature was80◦C with the duration of 3 h. Under such conditions, the retention yield of cellulose, extraction yields ofhemicellulose and lignin were 89.5%, 79.8% and 65.6%, respectively. Subsequently, the enzymatic hydrol-ysis of the solid residue was conducted by using the enzyme mixture of cellulase (20 FPU/g dry substrate)and -glucosidase (10 IU/g dry substrate). The enzymatic hydrolysis rate of glucan and xylan could reach62.8% and 79.4%, respectively. In addition, to study the property changes of corn stover before and aftertreatment, SEM, XRD and TGA analyses were performed, and the lignin extracted by formic acid was alsocharacterized by TGA and GPC; In this work, three main components (cellulose, hemicellulose, and lignin) of corn stover were fractionated effectively by formic acid. The effects of reaction temperature and time on the fractionation were investigated. It was found that the suitable conditions for the fractionation of corn stover were: the formic acid concentration was 88 wt.%, the ratio of solid to liquid was 1:13, and the treatment temperature was 80 C with the duration of 3 h. Under such conditions, the retention yield of cellulose, extraction yields of hemicellulose and lignin were 89.5%, 79.8% and 65.6%, respectively. Subsequently, the enzymatic hydrolysis of the solid residue was conducted by using the enzyme mixture of cellulase (20 FPU/g dry substrate) and beta-glucosidase (10IU/g dry substrate). The enzymatic hydrolysis rate of glucan and xylan could reach 62.8% and 79.4%, respectively. In addition, to study the property changes of corn stover before and after treatment, SEM, XRD and TGA analyses were performed, and the lignin extracted bylformic acid was also characterized by TGA and GPC. (C) 2013 Elsevier B.V. All rights reserved. |
文章类型 | Article |
关键词 | Corn Stover Formic Acid Fractionation Enzymatic Saccharification |
学科领域 | 绿色化学催化 |
WOS标题词 | Science & Technology ; Life Sciences & Biomedicine |
DOI | 10.1016/j.indcrop.2013.08.053 |
关键词[WOS] | PRETREATMENT ; CELLULOSE ; LIGNIN ; HYDROLYSIS ; EXTRACTION ; EXPLOSION ; PYROLYSIS ; CATALYSTS ; AMMONIA ; BIOMASS |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Agriculture |
WOS类目 | Agricultural Engineering ; Agronomy |
WOS记录号 | WOS:000326903600101 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/1654 |
专题 | 绿色化学催化研究组 |
作者单位 | Chinese Acad Sci, Key Lab Biofuels, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
推荐引用方式 GB/T 7714 | Yu, Guang,Li, Bin,Liu, Chao,et al. Fractionation of the main components of corn stover by formic acid and enzymatic saccharification of solid residue[J]. INDUSTRIAL CROPS AND PRODUCTS,2013,50(50):750-757. |
APA | Yu, Guang,Li, Bin,Liu, Chao,Zhang, Yuedong,Wang, Haisong,&Mu, Xindong.(2013).Fractionation of the main components of corn stover by formic acid and enzymatic saccharification of solid residue.INDUSTRIAL CROPS AND PRODUCTS,50(50),750-757. |
MLA | Yu, Guang,et al."Fractionation of the main components of corn stover by formic acid and enzymatic saccharification of solid residue".INDUSTRIAL CROPS AND PRODUCTS 50.50(2013):750-757. |
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