Facile synthesis of phosphorus doped graphitic carbon nitride polymers with enhanced visible-light photocatalytic activity | |
Zhang, L.; Chen, X.; Guan, J; Jiang, Y; Hou, T; Mu, X. | |
2013 | |
发表期刊 | Materials Research Bulletin |
卷号 | 48期号:9页码:3485-3491 |
摘要 | Phosphorus-doped carbon nitride materials were prepared by a one-pot green synthetic approach using dicyandiamide monomer and a phosphorus containing ionic liquid as precursors. The as-prepared materials were subjected to several characterizations and investigated as metal-free photocatalysts for the degradation of organic pollutants (dyes like Rhodamine B, Methyl orange) in aqueous solution under visible light. Results revealed that phosphorus-doped carbon nitride have a higher photocatalytic activity for decomposing Rhodamine B and Methyl orange in aqueous solution than undoped g-C3N4, which was attributed to the favorable textural, optical and electronic properties caused by doping with phosphorus heteroatoms into carbon nitride host. A facile postannealing treatment further improved the activity of the photocatalytic system, due to the higher surface area and smaller structural size in the postcalcined catalysts. The phosphorus-doped carbon nitride showed high visible-light photocatalytic activity, making them promising materials for a wide range of potential applications in photochemistry. |
关键词 | A. Nitrides A. Polymers A. Semiconductors D. Catalytic Properties D. Optical Properties |
学科领域 | 绿色化学催化 |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/1636 |
专题 | 绿色化学催化研究组 |
推荐引用方式 GB/T 7714 | Zhang, L.,Chen, X.,Guan, J,et al. Facile synthesis of phosphorus doped graphitic carbon nitride polymers with enhanced visible-light photocatalytic activity[J]. Materials Research Bulletin,2013,48(9):3485-3491. |
APA | Zhang, L.,Chen, X.,Guan, J,Jiang, Y,Hou, T,&Mu, X..(2013).Facile synthesis of phosphorus doped graphitic carbon nitride polymers with enhanced visible-light photocatalytic activity.Materials Research Bulletin,48(9),3485-3491. |
MLA | Zhang, L.,et al."Facile synthesis of phosphorus doped graphitic carbon nitride polymers with enhanced visible-light photocatalytic activity".Materials Research Bulletin 48.9(2013):3485-3491. |
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