Transition-metal nitride nanoparticles embedded in N-doped reduced graphene oxide: superior synergistic electrocatalytic materials for the counter electrodes of dye-sensitized solar cells | |
Zhang, Xiaoying1,2; Chen, Xiao1; Zhang, Kejun1,2; Pang, Shuping1; Zhou, Xinhong3; Xu, Hongxia1; Dong, Shanmu1; Han, Pengxian1; Zhang, Zhongyi1,2; Zhang, Chuanjian1,2; Cui, Guanglei1 | |
2013 | |
发表期刊 | JOURNAL OF MATERIALS CHEMISTRY A |
卷号 | 1期号:10页码:3340-3346 |
摘要 | Transition-metal nitride TMN (MoN, TiN, VN) nanoparticle-N-doped reduced graphene oxide (NG) hybrid materials are presented as alternative low-cost platinum-free counter electrodes for dye-sensitized solar cells (DSCs). A high concentration of active catalytic sites and an efficient electronic/ionic mixed conducting network generated by the nanostructure afford promising synergistic effects on the electrocatalytic characteristics for triiodide reduction. On the basis of these advantages, these nanostructured hybrid based cells deliver significantly enhanced photovoltaic performances. The efficiencies of devices employing VN-NG, TiN-NG and MoN-NG are 6.279%, 7.498% and 7.913% respectively, which are comparable with that of Pt devices (7.858%). Such a design strategy is facile, cost effective and versatile, thus it may be extended to other inexpensive platinum-free counter electrode materials. |
文章类型 | Article |
学科领域 | 仿生能源系统 |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1039/c2ta00608a |
关键词[WOS] | TITANIUM NITRIDE ; CARBON NANOTUBES ; LOW-COST ; REDOX ELECTROLYTE ; PERFORMANCE ; EFFICIENCY ; NANOCOMPOSITE ; CARBIDES ; FILMS |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
WOS类目 | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
WOS记录号 | WOS:000314784000019 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/1581 |
专题 | 仿生与固态能源系统研究组 |
作者单位 | 1.Chinese Acad Sci, Qingdao Key Lab Solar Energy Utilizat & Energy St, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Qingdao Univ Sci & Technol, Qingdao 266101, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Xiaoying,Chen, Xiao,Zhang, Kejun,et al. Transition-metal nitride nanoparticles embedded in N-doped reduced graphene oxide: superior synergistic electrocatalytic materials for the counter electrodes of dye-sensitized solar cells[J]. JOURNAL OF MATERIALS CHEMISTRY A,2013,1(10):3340-3346. |
APA | Zhang, Xiaoying.,Chen, Xiao.,Zhang, Kejun.,Pang, Shuping.,Zhou, Xinhong.,...&Cui, Guanglei.(2013).Transition-metal nitride nanoparticles embedded in N-doped reduced graphene oxide: superior synergistic electrocatalytic materials for the counter electrodes of dye-sensitized solar cells.JOURNAL OF MATERIALS CHEMISTRY A,1(10),3340-3346. |
MLA | Zhang, Xiaoying,et al."Transition-metal nitride nanoparticles embedded in N-doped reduced graphene oxide: superior synergistic electrocatalytic materials for the counter electrodes of dye-sensitized solar cells".JOURNAL OF MATERIALS CHEMISTRY A 1.10(2013):3340-3346. |
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