| A Novel Branched Polyoxymethylene Synthesized by Cationic Copolymerization of 1,3,5-Trioxane with 3-(Alkoxymethyl)-3-ethyloxetane | |
Mu, Youbing1 ; Jia, Mingchen1,2; Jiang, Wei3; Wan, Xiaobo1
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| 2013-12-01 | |
| 发表期刊 | MACROMOLECULAR CHEMISTRY AND PHYSICS
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| 卷号 | 214期号:23页码:2752-2760 |
| 摘要 | Novel branched polyoxymethylene copolymers are synthesized by cationic copolymerization of 1,3,5-trioxane (TOX) with 3-(alkoxymethyl)-3-ethyloxetane (ROX) using BF3 center dot Et2O as an initiator. Four oxetane derivatives with different side-chain lengths (from 1 to 6 carbons) are tested for copolymerization. The copolymer composition is controlled by the feed ratio of ROX, and influenced by the chain length of alkyl group on ROX. The incorporation ratio and side-chain length of the ROX unit have great influence on the thermomechanical properties and crystallinity of the copolymers. |
| 文章类型 | Article |
| 关键词 | Cationic Polymerization 3-(Alkoxymethyl)-3-ethyloxetane Copolymerization Polyoxymethylene Thermal Properties |
| 学科领域 | 生物基高分子材料 |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1002/macp.201300473 |
| 关键词[WOS] | RING-OPENING COPOLYMERIZATION ; ETHYLENE-OXIDE ; ACETAL COPOLYMER ; TRIOXANE ; POLYMERIZATION ; CRYSTALLIZATION ; 1,3-DIOXOLANE ; POLYACETALS ; BEHAVIOR ; OXETANE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| WOS记录号 | WOS:000328066200012 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/1555 |
| 专题 | 生物基及仿生高分子材料团队（过去） |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Shandong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Nanjing Univ, Sch Environm, Natl Engn Res Ctr Organ Pollut Control & Resource, State Key Lab Pollut & Resource Reuse, Nanjing 210093, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mu, Youbing,Jia, Mingchen,Jiang, Wei,et al. A Novel Branched Polyoxymethylene Synthesized by Cationic Copolymerization of 1,3,5-Trioxane with 3-(Alkoxymethyl)-3-ethyloxetane[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2013,214(23):2752-2760. |
| APA | Mu, Youbing,Jia, Mingchen,Jiang, Wei,&Wan, Xiaobo.(2013).A Novel Branched Polyoxymethylene Synthesized by Cationic Copolymerization of 1,3,5-Trioxane with 3-(Alkoxymethyl)-3-ethyloxetane.MACROMOLECULAR CHEMISTRY AND PHYSICS,214(23),2752-2760. |
| MLA | Mu, Youbing,et al."A Novel Branched Polyoxymethylene Synthesized by Cationic Copolymerization of 1,3,5-Trioxane with 3-(Alkoxymethyl)-3-ethyloxetane".MACROMOLECULAR CHEMISTRY AND PHYSICS 214.23(2013):2752-2760. |
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